This paper deals with a molecular gas-dynamics method applied to the accurate determination of the condensation coefficient of methanol vapor. The method consisted of an experiment using a shock tube and computations using a molecular gas-dynamics equation. The experiments were performed in such situations where the shift from a vapor–liquid equilibrium state to a nonequilibrium one is realized by a shock wave in a scale of molecular mean free time of vapor molecules. The temporal evolution in thickness of a liquid film formed on the shock-tube endwall behind a reflected shock wave is measured by an optical interferometer. By comparing the measured liquid-film thickness with numerical solutions for a polyatomic version of the Gaussian–BGK model of the Boltzmann equation, the condensation coefficient of methanol vapor is accurately determined in vapor–liquid nonequilibrium states. As a result, it is clear that the condensation coefficient is just unity very near to an equilibrium state, but is smaller far from the equilibrium state.
Experiments in Fluids – Springer Journals
Published: Mar 25, 2004
It’s your single place to instantly
discover and read the research
that matters to you.
Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.
All for just $49/month
Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly
Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.
Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.
Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.
All the latest content is available, no embargo periods.
“Hi guys, I cannot tell you how much I love this resource. Incredible. I really believe you've hit the nail on the head with this site in regards to solving the research-purchase issue.”Daniel C.
“Whoa! It’s like Spotify but for academic articles.”@Phil_Robichaud
“I must say, @deepdyve is a fabulous solution to the independent researcher's problem of #access to #information.”@deepthiw
“My last article couldn't be possible without the platform @deepdyve that makes journal papers cheaper.”@JoseServera