Microstructure analysis of ethylene/1-hexene co-polymers with embeddedrac-Et[Ind]2ZrCl2 metallocene catalyst

Microstructure analysis of ethylene/1-hexene co-polymers with embeddedrac-Et[Ind]2ZrCl2... Co-polymerization of ethylene and 1-hexene usingrac-Et[Ind]2ZrCl2/MAO catalyst embedded in polystyrene in liquid slurry process was examined. The embedded catalyst was prepared by polymerizing a small amount of styrene. The specific activities and bulk densities of the copolymers produced by the embedded catalyst were higher than those of the homogeneous catalyst. The produced co-polymer with embedded catalyst had more random distribution of 1-hexene at the similar co-monomer content than that with homogeneous catalyst. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Microstructure analysis of ethylene/1-hexene co-polymers with embeddedrac-Et[Ind]2ZrCl2 metallocene catalyst

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Publisher
Springer Netherlands
Copyright
Copyright © 2008 by Springer
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/BF03036926
Publisher site
See Article on Publisher Site

Abstract

Co-polymerization of ethylene and 1-hexene usingrac-Et[Ind]2ZrCl2/MAO catalyst embedded in polystyrene in liquid slurry process was examined. The embedded catalyst was prepared by polymerizing a small amount of styrene. The specific activities and bulk densities of the copolymers produced by the embedded catalyst were higher than those of the homogeneous catalyst. The produced co-polymer with embedded catalyst had more random distribution of 1-hexene at the similar co-monomer content than that with homogeneous catalyst.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Apr 15, 2009

References

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