Metal-containing polymers based on disalicylidenediamines and their electrophysical properties

Metal-containing polymers based on disalicylidenediamines and their electrophysical properties Metal-containing poly(disalicylidenediamines) exhibiting semiconductor properties were prepared by polycondensation of salicylidene derivatives of aromatic diamines with metal (Fe, Co, Ni, Cu) acetates. The data obtained confirm that the transfer of charge carriers in these polymers occurs along the chain through “nonclassical” polyconjugation zones formed via multiple intramolecular donor-acceptor interactions of lone electron pairs of the azomethine groups with the unoccupied d orbitals of the metal ions. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Metal-containing polymers based on disalicylidenediamines and their electrophysical properties

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Publisher
Pleiades Publishing
Copyright
Copyright © 2014 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427214110202
Publisher site
See Article on Publisher Site

Abstract

Metal-containing poly(disalicylidenediamines) exhibiting semiconductor properties were prepared by polycondensation of salicylidene derivatives of aromatic diamines with metal (Fe, Co, Ni, Cu) acetates. The data obtained confirm that the transfer of charge carriers in these polymers occurs along the chain through “nonclassical” polyconjugation zones formed via multiple intramolecular donor-acceptor interactions of lone electron pairs of the azomethine groups with the unoccupied d orbitals of the metal ions.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Mar 3, 2015

References

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