Mechanochemical synthesis of cerium(IV)-phosphonates

Mechanochemical synthesis of cerium(IV)-phosphonates J Mater Sci MECHANOCHEMICAL S YNTHESIS Mechanochemical Synthesis Mechanochemical synthesis of cerium(IV)- phosphonates 1,2 2 3 2, Manuel Wilke , Irina Akhmetova , Klaus Rademann , and Franziska Emmerling * Swiss Light Source, Material Science Beamline, Paul Scherrer Institute, 5232 Villigen PSI, Switzerland BAM Federal Institute for Materials Research and Testing, Richard-Willstätter-Straße 11, 12489 Berlin, Germany Department of Chemistry, Humboldt-Universität zu Berlin, Brook-Taylor-Str. 2, 12489 Berlin, Germany Received: 15 February 2018 ABSTRACT Accepted: 25 May 2018 The syntheses and crystal structures of two cerium(IV) phosphonates are pre- sented. Cerium(IV) bis(phenylphosphonate) Ce(O PC H ) 1 can be formed 3 6 5 2 Springer Science+Business from precipitation and mechanochemical reaction, whereas cerium(IV) bis(car- Media, LLC, part of Springer boxymethylphosphonate) monohydrate Ce(O PCH COOH)  H O 2 is only 3 2 2 2 Nature 2018 accessible via ball milling. All reactions proceed very fast and are completed within a short time span. In situ measurements for the syntheses of 1 show that the product occurs within seconds or a few minutes, respectively. The structures were solved from powder X-ray diffraction data. different dimensionality can easily be synthesized Introduction mechanochemically [19–22]. The mechanisms of mechanochemical reactions are not completely The synthesis http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Materials Science Springer Journals

Mechanochemical synthesis of cerium(IV)-phosphonates

Loading next page...
 
/lp/springer_journal/mechanochemical-synthesis-of-cerium-iv-phosphonates-CJ63sUwgsC
Publisher
Springer US
Copyright
Copyright © 2018 by Springer Science+Business Media, LLC, part of Springer Nature
Subject
Materials Science; Materials Science, general; Characterization and Evaluation of Materials; Polymer Sciences; Continuum Mechanics and Mechanics of Materials; Crystallography and Scattering Methods; Classical Mechanics
ISSN
0022-2461
eISSN
1573-4803
D.O.I.
10.1007/s10853-018-2507-x
Publisher site
See Article on Publisher Site

Abstract

J Mater Sci MECHANOCHEMICAL S YNTHESIS Mechanochemical Synthesis Mechanochemical synthesis of cerium(IV)- phosphonates 1,2 2 3 2, Manuel Wilke , Irina Akhmetova , Klaus Rademann , and Franziska Emmerling * Swiss Light Source, Material Science Beamline, Paul Scherrer Institute, 5232 Villigen PSI, Switzerland BAM Federal Institute for Materials Research and Testing, Richard-Willstätter-Straße 11, 12489 Berlin, Germany Department of Chemistry, Humboldt-Universität zu Berlin, Brook-Taylor-Str. 2, 12489 Berlin, Germany Received: 15 February 2018 ABSTRACT Accepted: 25 May 2018 The syntheses and crystal structures of two cerium(IV) phosphonates are pre- sented. Cerium(IV) bis(phenylphosphonate) Ce(O PC H ) 1 can be formed 3 6 5 2 Springer Science+Business from precipitation and mechanochemical reaction, whereas cerium(IV) bis(car- Media, LLC, part of Springer boxymethylphosphonate) monohydrate Ce(O PCH COOH)  H O 2 is only 3 2 2 2 Nature 2018 accessible via ball milling. All reactions proceed very fast and are completed within a short time span. In situ measurements for the syntheses of 1 show that the product occurs within seconds or a few minutes, respectively. The structures were solved from powder X-ray diffraction data. different dimensionality can easily be synthesized Introduction mechanochemically [19–22]. The mechanisms of mechanochemical reactions are not completely The synthesis

Journal

Journal of Materials ScienceSpringer Journals

Published: Jun 4, 2018

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Search

Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly

Organize

Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.

Access

Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve

Freelancer

DeepDyve

Pro

Price

FREE

$49/month
$360/year

Save searches from
Google Scholar,
PubMed

Create lists to
organize your research

Export lists, citations

Read DeepDyve articles

Abstract access only

Unlimited access to over
18 million full-text articles

Print

20 pages / month

PDF Discount

20% off