Mechanism of formation, structure, and properties of heat-resistant network polymers prepared by thermal curing of Rolivsans

Mechanism of formation, structure, and properties of heat-resistant network polymers prepared by... The mechanism of structural transformation of divinylaromatic formulations containing methacrylates of secondary aromatic alcohols and diols into heat-resistant and strong glassy network polymers was examined. The structure and properties of the products were studied. The Rolivsans prepared demonstrate the possibility of chemical construction of high-temperature thermosets in which molecules with thermally stable ether groups and labile ester groups, providing excellent process properties of the formulation in the low-temperature step of the reactive forming, are capable of transforming into heat-resistant network polymers. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Mechanism of formation, structure, and properties of heat-resistant network polymers prepared by thermal curing of Rolivsans

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Publisher
SP MAIK Nauka/Interperiodica
Copyright
Copyright © 2010 by Pleiades Publishing, Ltd.
Subject
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427210070190
Publisher site
See Article on Publisher Site

Abstract

The mechanism of structural transformation of divinylaromatic formulations containing methacrylates of secondary aromatic alcohols and diols into heat-resistant and strong glassy network polymers was examined. The structure and properties of the products were studied. The Rolivsans prepared demonstrate the possibility of chemical construction of high-temperature thermosets in which molecules with thermally stable ether groups and labile ester groups, providing excellent process properties of the formulation in the low-temperature step of the reactive forming, are capable of transforming into heat-resistant network polymers.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Aug 17, 2010

References

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