Mechanism of cathodic reduction of cobalt pyrophosphate complex

Mechanism of cathodic reduction of cobalt pyrophosphate complex Potentiostatic and potentiodynamic methods were employed to study the kinetics of electrochemical reduction of the pyrophosphate cobalt complex to the metal from electrolytes of various compositions in the atmosphere of hydrogen. The reaction orders of cobalt reduction with respect to pyrophosphate anions and hydroxy ions were found. A stage-by-stage mechanism of the cathodic reduction of cobalt was suggested. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Mechanism of cathodic reduction of cobalt pyrophosphate complex

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Publisher
SP MAIK Nauka/Interperiodica
Copyright
Copyright © 2012 by Pleiades Publishing, Ltd.
Subject
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427212050096
Publisher site
See Article on Publisher Site

Abstract

Potentiostatic and potentiodynamic methods were employed to study the kinetics of electrochemical reduction of the pyrophosphate cobalt complex to the metal from electrolytes of various compositions in the atmosphere of hydrogen. The reaction orders of cobalt reduction with respect to pyrophosphate anions and hydroxy ions were found. A stage-by-stage mechanism of the cathodic reduction of cobalt was suggested.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Jun 15, 2012

References

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