Mechanical and dielectric behavior of poly(vinylidene)–poly(arylene ether nitrile) composites as film capacitors for energy storage applications

Mechanical and dielectric behavior of poly(vinylidene)–poly(arylene ether nitrile) composites... Novel polymer composites PEN/PVDF were prepared from poly(arylene ether nitrile) (PEN) and poly(vinylidene fluoride) (PVDF) via solution mixing. Due to the toughening effect of PVDF, PEN/PVDF blends with 5 wt % PVDF exhibit higher tensile strength (106 MPa) and breaking elongation (8.09%) than pure PEN does. Because of introduction of PVDF and interfacial polarization, the dielectric constant of PEN/PVDF blends at 1 kHz and room temperature increases from 3.3 to 4.5 with increasing content of PVDF. The dissipation factor (tanδ) of PEN/PVDF blends is relatively low (<0.04) in a very wide frequency range from 250 Hz to 100 kHz. The PEN/PVDF blends show certain piezoelectric behavior (d 33 from 0.9 to 1 pC/N) due to the contribution of PVDF. After polarization, the piezoelectric coefficient d 33 somewhat increases. The results suggest that PEN/PVDF blends will have potential application in electronic information fields, especially in film capacitors. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Mechanical and dielectric behavior of poly(vinylidene)–poly(arylene ether nitrile) composites as film capacitors for energy storage applications

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Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S10704272150120198
Publisher site
See Article on Publisher Site

Abstract

Novel polymer composites PEN/PVDF were prepared from poly(arylene ether nitrile) (PEN) and poly(vinylidene fluoride) (PVDF) via solution mixing. Due to the toughening effect of PVDF, PEN/PVDF blends with 5 wt % PVDF exhibit higher tensile strength (106 MPa) and breaking elongation (8.09%) than pure PEN does. Because of introduction of PVDF and interfacial polarization, the dielectric constant of PEN/PVDF blends at 1 kHz and room temperature increases from 3.3 to 4.5 with increasing content of PVDF. The dissipation factor (tanδ) of PEN/PVDF blends is relatively low (<0.04) in a very wide frequency range from 250 Hz to 100 kHz. The PEN/PVDF blends show certain piezoelectric behavior (d 33 from 0.9 to 1 pC/N) due to the contribution of PVDF. After polarization, the piezoelectric coefficient d 33 somewhat increases. The results suggest that PEN/PVDF blends will have potential application in electronic information fields, especially in film capacitors.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Mar 3, 2016

References

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