Maximum filling principle and sublattice characteristics for the atoms of period 6 elements

Maximum filling principle and sublattice characteristics for the atoms of period 6 elements The most important characteristics of the Voronoi-Dirichlet polyhedra (VDP) were determined for the 88223 crystallographically different A atoms (A = Cs, Ba, La, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Tl, Pb, or Bi) in sublattices containing chemically identical atoms in the crystal structures of 52370 inorganic and organoelement compounds. Irrespective of the nature of the A element, the VDP have most often 14 faces, the Fedorov cuboctahedron being the most abundant VDP type. The metal atoms A were found to have, most often, C 1 site symmetry (76% of cases) and also C s , C 2, C i , and C 2v site symmetries (7 to 2%). Certain relationships were shown to exist between the nature of the metal atom and the preferred symmetry of the sites it occupies in the crystal structures. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Maximum filling principle and sublattice characteristics for the atoms of period 6 elements

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Publisher
Nauka/Interperiodica
Copyright
Copyright © 2006 by Pleiades Publishing, Inc.
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328406110066
Publisher site
See Article on Publisher Site

Abstract

The most important characteristics of the Voronoi-Dirichlet polyhedra (VDP) were determined for the 88223 crystallographically different A atoms (A = Cs, Ba, La, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Tl, Pb, or Bi) in sublattices containing chemically identical atoms in the crystal structures of 52370 inorganic and organoelement compounds. Irrespective of the nature of the A element, the VDP have most often 14 faces, the Fedorov cuboctahedron being the most abundant VDP type. The metal atoms A were found to have, most often, C 1 site symmetry (76% of cases) and also C s , C 2, C i , and C 2v site symmetries (7 to 2%). Certain relationships were shown to exist between the nature of the metal atom and the preferred symmetry of the sites it occupies in the crystal structures.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Nov 6, 2006

References

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