Magnetic Fe3O4 nanoparticles supported amine: a new, sustainable and environmentally benign catalyst for condensation reactions

Magnetic Fe3O4 nanoparticles supported amine: a new, sustainable and environmentally benign... Keywords Magnetically separable catalyst  DETA-Fe O  Knoevenagel 3 4 condensation  2,3-dihydroquinazoline-4(1H)-ones  Water  Environmental Introduction The easy separation and reusability of catalysts is a key factor in the selection of catalytic processes [1]. Catalysis chemical reactions by an acid or a base immobilized on magnetic nanocatalysts (MNPs) have become a hot research topic in modern catalysis research [2]. Among the various magnetic NPs employed as the core magnetic support, Fe O NPs have received special attention due to their 3 4 simple preparation, low toxicity, abundance and unique activities, which allow the use of mild reaction conditions in chemical transformations to achieve the corresponding final products [3–6]. In addition, catalysis research under aqueous media is an appropriate direction for the future of organic synthesis, in particular from the point of view of green synthetic chemistry [7]. Knoevenagel condensation of aldehydes with active methylene compounds is a well-known and extensively studied strategy for carbon–carbon bond formation in organic synthesis [8], because Knoevenagel products (namely the a, b -unsaturated 123 Magnetic Fe O nanoparticles supported amine… 4815 3 4 products or synthesized alkene) play a vital role in the synthesis of fine chemicals [9], therapeutic drugs [10], http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Magnetic Fe3O4 nanoparticles supported amine: a new, sustainable and environmentally benign catalyst for condensation reactions

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Publisher
Springer Journals
Copyright
Copyright © 2017 by Springer Science+Business Media Dordrecht
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-017-2914-7
Publisher site
See Article on Publisher Site

Abstract

Keywords Magnetically separable catalyst  DETA-Fe O  Knoevenagel 3 4 condensation  2,3-dihydroquinazoline-4(1H)-ones  Water  Environmental Introduction The easy separation and reusability of catalysts is a key factor in the selection of catalytic processes [1]. Catalysis chemical reactions by an acid or a base immobilized on magnetic nanocatalysts (MNPs) have become a hot research topic in modern catalysis research [2]. Among the various magnetic NPs employed as the core magnetic support, Fe O NPs have received special attention due to their 3 4 simple preparation, low toxicity, abundance and unique activities, which allow the use of mild reaction conditions in chemical transformations to achieve the corresponding final products [3–6]. In addition, catalysis research under aqueous media is an appropriate direction for the future of organic synthesis, in particular from the point of view of green synthetic chemistry [7]. Knoevenagel condensation of aldehydes with active methylene compounds is a well-known and extensively studied strategy for carbon–carbon bond formation in organic synthesis [8], because Knoevenagel products (namely the a, b -unsaturated 123 Magnetic Fe O nanoparticles supported amine… 4815 3 4 products or synthesized alkene) play a vital role in the synthesis of fine chemicals [9], therapeutic drugs [10],

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Mar 25, 2017

References

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