Chemical processes leading to inactivation of vanadium sulfuric acid catalysts by arsenic(III) oxide vapor were studied. The interaction and solubility in the system VO(H2AsO4)2-VOAsO4-H3AsO4-H2O and the composition of oxovanadium arsenate in a mixed oxidation state, used as a starting substance in synthesis of (VIVO)(VVO)2(As2O7)2, were examined.
Russian Journal of Applied Chemistry – Springer Journals
Published: May 25, 2006
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