Laser flash photolysis study of methanol addition to the C60 radical cation

Laser flash photolysis study of methanol addition to the C60 radical cation Stable alcohol adducts of buckminsterfullerene (C60) can be created via addition to C60 radical cations. The radical cations were generated by photosensitized electron transfer from C60 in a solution of N-methylacridinium hexafluorophosphate and biphenyl. Growth and decay of the C60 radical cation population was monitored by transient absorption spectroscopy at 980 nm. The lifetime of the transient decreases in the presence of methanol, supporting trapping of the radical cation. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Laser flash photolysis study of methanol addition to the C60 radical cation

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Publisher
Springer Netherlands
Copyright
Copyright © 1997 by Springer
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/156856797X00222
Publisher site
See Article on Publisher Site

Abstract

Stable alcohol adducts of buckminsterfullerene (C60) can be created via addition to C60 radical cations. The radical cations were generated by photosensitized electron transfer from C60 in a solution of N-methylacridinium hexafluorophosphate and biphenyl. Growth and decay of the C60 radical cation population was monitored by transient absorption spectroscopy at 980 nm. The lifetime of the transient decreases in the presence of methanol, supporting trapping of the radical cation.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Apr 14, 2009

References

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