Experimental studies of acrylamide polymerization initiated by a redox system in concentrated aqueous solutions were conducted under isothermal conditions. A mathematical model of the acrylamide polymerization in concentrated aqueous solutions, which allows predicting the monomer conversion and molecular weight of polyacrylamide synthesized, was proposed in view of a change in a initiation efficiency and chain termination rate upon an increase in a viscosity of the polymerization system. A comparison of experimental data with calculations was performed based on the developed mathematical model.
Russian Journal of Applied Chemistry – Springer Journals
Published: Apr 16, 2015
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