Kinetics of liquid-phase benzene hydrogenation on Rh/C

Kinetics of liquid-phase benzene hydrogenation on Rh/C Liquid-phase hydrogenation of benzene was studied over Rh catalyst supported on a carbon carrier sibunit between 13 and 100°C and in a hydrogen pressure range of 20–100 bar. Kinetic data were obtained under mass transfer-free conditions. Similar to gas-phase hydrogenation activity, a maximum with temperature was observed. A kinetic model consistent with thermodynamics was applied for numerical parameter estimation. Good correspondence between the experimental and calculated data was achieved. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Kinetics of liquid-phase benzene hydrogenation on Rh/C

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Publisher
Springer Netherlands
Copyright
Copyright © 2009 by Springer Science+Business Media B.V.
Subject
Chemistry; Inorganic Chemistry ; Physical Chemistry ; Catalysis
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-008-0005-5
Publisher site
See Article on Publisher Site

Abstract

Liquid-phase hydrogenation of benzene was studied over Rh catalyst supported on a carbon carrier sibunit between 13 and 100°C and in a hydrogen pressure range of 20–100 bar. Kinetic data were obtained under mass transfer-free conditions. Similar to gas-phase hydrogenation activity, a maximum with temperature was observed. A kinetic model consistent with thermodynamics was applied for numerical parameter estimation. Good correspondence between the experimental and calculated data was achieved.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Jan 14, 2009

References

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