Cobalt carbonyls was prepared from an aqueous solution of cobalt acetate containing or not containing pyridine in the presence of the organic solvent immiscible with water. The product in the form of an organic solution can be used as hydroformylation catalyst. The kinetic equation taking into account the distribution of the reagents between the three phases was derived. The apparent rate constants and activation energies were calculated.
Russian Journal of Applied Chemistry – Springer Journals
Published: Oct 13, 2004
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