Kinetics and thermoluminescence glow curve study of Ba2MgSi2O7:Eu3+, Dy3+

Kinetics and thermoluminescence glow curve study of Ba2MgSi2O7:Eu3+, Dy3+ This paper reports thermoluminescence glow curves of Eu3+, Dy3+-doped Ba2MgSi2O7 phosphor for different UV exposure times. Kinetic data were evaluated by the peak-shape method. The glow curves shift toward higher intensity with increasing exposure time to UV at 365 nm. When the heating rate was 5 °C s−1, peaks were observed at 101.76, 109.69, 102.67, and 104.05 °C, respectively, after UV exposure for 5, 10, 15, and 20 min. The glow peaks are indicative of second-order kinetics. Different kinetic data, i.e. trap depth, order of kinetics, activation energy, and frequency factor were also calculated. To evaluate the persistence characteristics of the luminescence of the phosphor, the lifetime of the charge in the trap was calculated; it was 348, 660, 368, and 428 s for UV exposure of 5, 10, 15, and 20 min, which indicates the luminescence of the phosphor is persistent. Research on Chemical Intermediates Springer Journals

Kinetics and thermoluminescence glow curve study of Ba2MgSi2O7:Eu3+, Dy3+

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Springer Netherlands
Copyright © 2013 by Springer Science+Business Media Dordrecht
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
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