Ion coordination in aqueous solutions of cerium nitrate from X-ray diffraction data

Ion coordination in aqueous solutions of cerium nitrate from X-ray diffraction data Aqueous solutions of cerium nitrate were studied by X-ray diffraction over a wide concentration range under standard conditions. The presence of prepeaks on experimental X-ray diffraction intensity curves can be explained by the long-range order of ions. With a decrease in the concentration of cerium nitrate, the pseudoperiodic distribution of composite cation-anion complexes changes to an even interionic distribution in the water network of a solvent, which is reflected by the intensity curves. The experimental radial distribution functions were calculated and interpreted. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Ion coordination in aqueous solutions of cerium nitrate from X-ray diffraction data

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Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328414120045
Publisher site
See Article on Publisher Site

Abstract

Aqueous solutions of cerium nitrate were studied by X-ray diffraction over a wide concentration range under standard conditions. The presence of prepeaks on experimental X-ray diffraction intensity curves can be explained by the long-range order of ions. With a decrease in the concentration of cerium nitrate, the pseudoperiodic distribution of composite cation-anion complexes changes to an even interionic distribution in the water network of a solvent, which is reflected by the intensity curves. The experimental radial distribution functions were calculated and interpreted.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Jan 7, 2015

References

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