Aqueous solutions of cerium nitrate were studied by X-ray diffraction over a wide concentration range under standard conditions. The presence of prepeaks on experimental X-ray diffraction intensity curves can be explained by the long-range order of ions. With a decrease in the concentration of cerium nitrate, the pseudoperiodic distribution of composite cation-anion complexes changes to an even interionic distribution in the water network of a solvent, which is reflected by the intensity curves. The experimental radial distribution functions were calculated and interpreted.
Russian Journal of Coordination Chemistry – Springer Journals
Published: Jan 7, 2015
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