A novel Cd(II) coordination polymer [Cd(C4H11N2)(μ-Cl)2Cl] n ·nH2O with a supramolecular structure has been synthesized by reaction of CdCl22·5H2O with piperazine. The compound was investigated by X-ray diffraction, electrochemistry, and IR spectroscopy. The CdCl3(C4H11N2)·H2O entity in the compound forms a 1D coordination polymer as a result of the bridging function of the chlorine atoms Cd–Cl2–Cd. Adjacent 1D coordination polymers are connected by (O,N,C)–H…Cl, (O,N)–H…Cl, and N–H…O hydrogen bonds, generating a three-dimensional supramolecular network. With this atomic arrangement, the complex can form an electroactive film on a platinum electrode by anodic oxidation in acetonitrile solution.
Research on Chemical Intermediates – Springer Journals
Published: Apr 5, 2015
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