Chlorination of polydienes with a high content of vinyl units without using gaseous chlorine or HCl was studied. The following methods were tested: chlorination, hydrochlorination, addition of dichlorocarbenes to double bonds in two-phase systems using phase-transfer catalysts, and addition of dichlorocarbenes under homogeneous conditions in the presence of a catalytic system.
Russian Journal of Applied Chemistry – Springer Journals
Published: Aug 17, 2010
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