The IR spectra of M(Acac)3 (M = Al, Ga, and In; Acac−1 is the acetylacetonate ion) and their isotope-substituted analogs were calculated by the Hartree-Fock-Roothaan method. The results obtained and available literature data were used to assign the absorption bands. A correlation was found between the force constants of the M-O bond and the stability constants of the complexes M(Acac)3.
Russian Journal of Coordination Chemistry – Springer Journals
Published: Aug 6, 2006
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