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Interpretation of the EPR spectral parameters for coordination compounds

Interpretation of the EPR spectral parameters for coordination compounds ISSN 1070-3284, Russian Journal of Coordination Chemistry, 2006, Vol. 32, No. 3, pp. 231. © Pleiades Publishing, Inc., 2006. Original Russian Text © V. I. Murav’ev, 2006, published in Koordinatsionnaya Khimiya, 2006, Vol. 32, No. 3, pp. 240. LETTER TO THE EDITOR Interpretation of the EPR Spectral Parameters for Coordination Compounds V. I. Murav’ev Izmeritel' Research and Production Center, Ulyanovsk, Russia Received July 1, 2005 DOI: 10.1134/S1070328406030110 exp Analysis of the experimental parameters of the EPR and g > 2.0023) caused by the effect of CTS in the || spectra, in particular, those of transition metal ions, molybdenum(V) oxyhalide complexes (4d ) [4]. The shows that interpretation of the EPR parameters exp requires, in some cases, data on the electron distribu- anomalous values g > 2.0023 for the low-spin chro- tion not only in the antibonding but also in the bonding mium(I) nitrosyl complexes (3d ) have also been states of the paramagnetic complex. These data are explained in terms of this method. The SP and vibronic needed for interpretation in those cases where the spec- coupling effects on the isotropic parts of the A-tensor components, inducing an anomalous behavior of these tral parameters exhibit anomalous behavior related to http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Interpretation of the EPR spectral parameters for coordination compounds

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Interpretation of the EPR spectral parameters for coordination compounds

Abstract

ISSN 1070-3284, Russian Journal of Coordination Chemistry, 2006, Vol. 32, No. 3, pp. 231. © Pleiades Publishing, Inc., 2006. Original Russian Text © V. I. Murav’ev, 2006, published in Koordinatsionnaya Khimiya, 2006, Vol. 32, No. 3, pp. 240. LETTER TO THE EDITOR Interpretation of the EPR Spectral Parameters for Coordination Compounds V. I. Murav’ev Izmeritel' Research and Production Center, Ulyanovsk, Russia Received July 1, 2005 DOI: 10.1134/S1070328406030110 exp...
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Publisher
Springer Journals
Copyright
Copyright © 2006 by Pleiades Publishing, Inc.
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry
ISSN
1070-3284
eISSN
1608-3318
DOI
10.1134/S1070328406030110
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See Article on Publisher Site

Abstract

ISSN 1070-3284, Russian Journal of Coordination Chemistry, 2006, Vol. 32, No. 3, pp. 231. © Pleiades Publishing, Inc., 2006. Original Russian Text © V. I. Murav’ev, 2006, published in Koordinatsionnaya Khimiya, 2006, Vol. 32, No. 3, pp. 240. LETTER TO THE EDITOR Interpretation of the EPR Spectral Parameters for Coordination Compounds V. I. Murav’ev Izmeritel' Research and Production Center, Ulyanovsk, Russia Received July 1, 2005 DOI: 10.1134/S1070328406030110 exp Analysis of the experimental parameters of the EPR and g > 2.0023) caused by the effect of CTS in the || spectra, in particular, those of transition metal ions, molybdenum(V) oxyhalide complexes (4d ) [4]. The shows that interpretation of the EPR parameters exp requires, in some cases, data on the electron distribu- anomalous values g > 2.0023 for the low-spin chro- tion not only in the antibonding but also in the bonding mium(I) nitrosyl complexes (3d ) have also been states of the paramagnetic complex. These data are explained in terms of this method. The SP and vibronic needed for interpretation in those cases where the spec- coupling effects on the isotropic parts of the A-tensor components, inducing an anomalous behavior of these tral parameters exhibit anomalous behavior related to

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Russian Journal of Coordination Chemistry – Springer Journals

Published: Mar 20, 2006

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