Interaction of [В10H10]2– and [В12H12]2– with nitro compounds

Interaction of [В10H10]2– and [В12H12]2– with nitro compounds The interaction of the [B10H10]2– and [B12H12]2– anions with aliphatic and aromatic nitro compounds (RNO2, where R = Et, n-Pr, i-Pr, tert-Bu, Ph) has been studied under irradiation with visible and UV light. It has been shown that, depending on the reaction conditions, both mono- and disubstituted nitro-closo-decaborates can be selectively obtained in yields up to 50%. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

Interaction of [В10H10]2– and [В12H12]2– with nitro compounds

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Publisher
Springer Journals
Copyright
Copyright © 2017 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
D.O.I.
10.1134/S0012500817110088
Publisher site
See Article on Publisher Site

Abstract

The interaction of the [B10H10]2– and [B12H12]2– anions with aliphatic and aromatic nitro compounds (RNO2, where R = Et, n-Pr, i-Pr, tert-Bu, Ph) has been studied under irradiation with visible and UV light. It has been shown that, depending on the reaction conditions, both mono- and disubstituted nitro-closo-decaborates can be selectively obtained in yields up to 50%.

Journal

Doklady ChemistrySpringer Journals

Published: Dec 2, 2017

References

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