Insights into the crystal structure of a polyoxomolybdate(VI) anion stabilized by ammonium cation: Inputs from X-ray diffraction and Hirshfeld surface analysis

Insights into the crystal structure of a polyoxomolybdate(VI) anion stabilized by ammonium... A new polyoxomolybdate complex with chemical formula [NH2(CH3)2]4[Mo8O26] (I) has been synthesized and structurally characterized. Single-crystal X-ray analysis of compound I reveals that the ammonium cation generates an intricate 2D supramolecular architecture (CIF file CCDC no. 1026577). The detail analyses of Hirschfeld surface and fingerprint plots gave a mode of non-covalent interactions in the title compound. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Insights into the crystal structure of a polyoxomolybdate(VI) anion stabilized by ammonium cation: Inputs from X-ray diffraction and Hirshfeld surface analysis

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Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328415090079
Publisher site
See Article on Publisher Site

Abstract

A new polyoxomolybdate complex with chemical formula [NH2(CH3)2]4[Mo8O26] (I) has been synthesized and structurally characterized. Single-crystal X-ray analysis of compound I reveals that the ammonium cation generates an intricate 2D supramolecular architecture (CIF file CCDC no. 1026577). The detail analyses of Hirschfeld surface and fingerprint plots gave a mode of non-covalent interactions in the title compound.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Sep 2, 2015

References

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