Influence of the structure of oxirane-containing compounds on curing of poly-N-methyl-5-vinyltetrazole

Influence of the structure of oxirane-containing compounds on curing of... Comparative analysis of the curing performance of epoxy-containing cross-linking agents of different structure in vulcanization of a promising binder for energetic systems, poly-N-methyl-5-vinyltetrazole prepared by the modification procedure and containing residual N–H-unsubstituted tetrazole fragments, was made. Cross-linking of polymer chains of the binder is a result of alkylation of the residual N–H-unsubstituted tetrazole rings in poly-N-methyl-5-vinyltetrazole macromolecules with oxirane rings of the second reactant. Curing of poly-N-methyl-5-vinyltetrazole in the presence of macromolecular curing agents, carbon-chain polymers containing oxirane rings in pendant chains, at temperatures lower than 100°С occurs in a considerably narrower time interval compared to curing with low-molecular-mass epoxy resin. Russian Journal of Applied Chemistry Springer Journals

Influence of the structure of oxirane-containing compounds on curing of poly-N-methyl-5-vinyltetrazole

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Pleiades Publishing
Copyright © 2016 by Pleiades Publishing, Ltd.
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
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