Influence of the Structure of Anion-Exchange Resin on Complexation with Transition Metal Ions

Influence of the Structure of Anion-Exchange Resin on Complexation with Transition Metal Ions Polarography and potentiometry was applied to study the influence exerted by the degree of crosslinking of an ion-exchange resin based on allyl bromide, diglycidil ether of resorcinol, and polyethylenepolyamine on its complexing ability. The shift of the potential of half-wave of reduction of the complex ion and data of potentiometric titration with and without complexing metal were used to calculate the coordination numbers and stability constants of complexes with cations of various metals. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Influence of the Structure of Anion-Exchange Resin on Complexation with Transition Metal Ions

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Publisher
Kluwer Academic Publishers-Plenum Publishers
Copyright
Copyright © 2003 by MAIK “Nauka/Interperiodica”
Subject
Chemistry; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1023/A:1024682024613
Publisher site
See Article on Publisher Site

Abstract

Polarography and potentiometry was applied to study the influence exerted by the degree of crosslinking of an ion-exchange resin based on allyl bromide, diglycidil ether of resorcinol, and polyethylenepolyamine on its complexing ability. The shift of the potential of half-wave of reduction of the complex ion and data of potentiometric titration with and without complexing metal were used to calculate the coordination numbers and stability constants of complexes with cations of various metals.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Oct 4, 2004

References

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