Influence of Solvents on the Rate of Thermal Decomposition of Peroxydecanoic Acid

Influence of Solvents on the Rate of Thermal Decomposition of Peroxydecanoic Acid Thermal decomposition of peroxydecanoic acid has been investigated in various organic solvents. The reaction medium significantly affects the rate of peroxydecanoic acid thermal decomposition. It has been shown that primary homolytic decomposition of peroxy group is followed by induced radical chain decomposition reactions. The solvent nature influences both primary homolytic decomposition and secondary induced reactions. The correlation equations relating kinetic parameters of peroxydecanoic acid thermolysis and basic solvent properties have been derived. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of General Chemistry Springer Journals

Influence of Solvents on the Rate of Thermal Decomposition of Peroxydecanoic Acid

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Publisher
Springer Journals
Copyright
Copyright © 2018 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general
ISSN
1070-3632
eISSN
1608-3350
D.O.I.
10.1134/S1070363218020020
Publisher site
See Article on Publisher Site

Abstract

Thermal decomposition of peroxydecanoic acid has been investigated in various organic solvents. The reaction medium significantly affects the rate of peroxydecanoic acid thermal decomposition. It has been shown that primary homolytic decomposition of peroxy group is followed by induced radical chain decomposition reactions. The solvent nature influences both primary homolytic decomposition and secondary induced reactions. The correlation equations relating kinetic parameters of peroxydecanoic acid thermolysis and basic solvent properties have been derived.

Journal

Russian Journal of General ChemistrySpringer Journals

Published: Mar 15, 2018

References

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