Influence of phosphazenes of various structures on the curing parameters and thermal oxidative degradation of oligomethylphenylsiloxane

Influence of phosphazenes of various structures on the curing parameters and thermal oxidative... Scientific and applied aspects of possible use of cyclic phosphazenes, by-products from phosphonitrilic anilide synthesis, as thermal stabilizers were considered. The solubility and thermal oxidative stability of phosphonitrile anilide trimer and tetramer were studied, the dependence of the curing parameters of oligomethylphenylsiloxane compositions (gel time, temperature intervals of curing) from the structure of the modifying additive was examined, and the resistance of compositions based on oligomethylphenylsiloxane modified with linear and cyclic oligophosphazenes to thermal oxidation at 350°C was evaluated. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Influence of phosphazenes of various structures on the curing parameters and thermal oxidative degradation of oligomethylphenylsiloxane

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Publisher
Springer Journals
Copyright
Copyright © 2014 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427214090250
Publisher site
See Article on Publisher Site

Abstract

Scientific and applied aspects of possible use of cyclic phosphazenes, by-products from phosphonitrilic anilide synthesis, as thermal stabilizers were considered. The solubility and thermal oxidative stability of phosphonitrile anilide trimer and tetramer were studied, the dependence of the curing parameters of oligomethylphenylsiloxane compositions (gel time, temperature intervals of curing) from the structure of the modifying additive was examined, and the resistance of compositions based on oligomethylphenylsiloxane modified with linear and cyclic oligophosphazenes to thermal oxidation at 350°C was evaluated.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Dec 30, 2014

References

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