Influence of heteroligand complexation on the thermal, photoluminescent, and film-forming properties of some aromatic terbium(III) carboxylates

Influence of heteroligand complexation on the thermal, photoluminescent, and film-forming... With homoligand TbL3 and heteroligand complexes TbL3(Q)n (HL = HSal (salicylic acid) and HPA (2-anilinobenzoic acid); Q = TPPO (triphenylphosphine oxide) and TOPO (tri(n-octyl)phosphine oxide); n = 1 or 2) as examples, it was shown that heteroligand complexation affects not only the thermal and photoluminescent properties but also the quality of films obtained by centrifugation: the root-mean-square roughness changes in the order TbL3Q > TbL3(Q)2 ≈ TbL3. This is due to different association degrees of the complexes in solution, which was confirmed by MALDI-TOF MS data. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Influence of heteroligand complexation on the thermal, photoluminescent, and film-forming properties of some aromatic terbium(III) carboxylates

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Publisher
Nauka/Interperiodica
Copyright
Copyright © 2006 by Pleiades Publishing, Inc.
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328406120086
Publisher site
See Article on Publisher Site

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