Improvement of a process for preparing peracetic acid by the reaction of acetic acid with hydrogen peroxide in aqueous solutions, catalyzed by ion-exchange resins

Improvement of a process for preparing peracetic acid by the reaction of acetic acid with... The effect of Amberlyst 15Dry™ cation-exchange resin on the reaction of peracetic acid formation from acetic acid and hydrogen peroxide in aqueous solution was studied. The pathways of available oxygen consumption were determined. The noncatalytic synthesis is accompanied by spontaneous decomposition of the peracid formed, which sharply decelerates on introducing Amberlyst 15Dry catalyst into the reaction mixture. Comparison of the kinetic relationships of the processes occurring in batch and flow-through reactors shows that in the latter case the process is characterized by diffusion hindrance. A kinetic model of the process with the parameters ensuring adequate mathematical description of the data obtained was suggested. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Improvement of a process for preparing peracetic acid by the reaction of acetic acid with hydrogen peroxide in aqueous solutions, catalyzed by ion-exchange resins

Loading next page...
 
/lp/springer_journal/improvement-of-a-process-for-preparing-peracetic-acid-by-the-reaction-ee5GGYAGkA
Publisher
Springer Journals
Copyright
Copyright © 2016 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427216030125
Publisher site
See Article on Publisher Site

Abstract

The effect of Amberlyst 15Dry™ cation-exchange resin on the reaction of peracetic acid formation from acetic acid and hydrogen peroxide in aqueous solution was studied. The pathways of available oxygen consumption were determined. The noncatalytic synthesis is accompanied by spontaneous decomposition of the peracid formed, which sharply decelerates on introducing Amberlyst 15Dry catalyst into the reaction mixture. Comparison of the kinetic relationships of the processes occurring in batch and flow-through reactors shows that in the latter case the process is characterized by diffusion hindrance. A kinetic model of the process with the parameters ensuring adequate mathematical description of the data obtained was suggested.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Jun 15, 2016

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Search

Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly

Organize

Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.

Access

Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve

Freelancer

DeepDyve

Pro

Price

FREE

$49/month
$360/year

Save searches from
Google Scholar,
PubMed

Create lists to
organize your research

Export lists, citations

Read DeepDyve articles

Abstract access only

Unlimited access to over
18 million full-text articles

Print

20 pages / month

PDF Discount

20% off