Improvement of a process for preparing peracetic acid by the reaction of acetic acid with hydrogen peroxide in aqueous solutions, catalyzed by ion-exchange resins

Improvement of a process for preparing peracetic acid by the reaction of acetic acid with... The effect of Amberlyst 15Dry™ cation-exchange resin on the reaction of peracetic acid formation from acetic acid and hydrogen peroxide in aqueous solution was studied. The pathways of available oxygen consumption were determined. The noncatalytic synthesis is accompanied by spontaneous decomposition of the peracid formed, which sharply decelerates on introducing Amberlyst 15Dry catalyst into the reaction mixture. Comparison of the kinetic relationships of the processes occurring in batch and flow-through reactors shows that in the latter case the process is characterized by diffusion hindrance. A kinetic model of the process with the parameters ensuring adequate mathematical description of the data obtained was suggested. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Improvement of a process for preparing peracetic acid by the reaction of acetic acid with hydrogen peroxide in aqueous solutions, catalyzed by ion-exchange resins

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Publisher
Pleiades Publishing
Copyright
Copyright © 2016 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427216030125
Publisher site
See Article on Publisher Site

Abstract

The effect of Amberlyst 15Dry™ cation-exchange resin on the reaction of peracetic acid formation from acetic acid and hydrogen peroxide in aqueous solution was studied. The pathways of available oxygen consumption were determined. The noncatalytic synthesis is accompanied by spontaneous decomposition of the peracid formed, which sharply decelerates on introducing Amberlyst 15Dry catalyst into the reaction mixture. Comparison of the kinetic relationships of the processes occurring in batch and flow-through reactors shows that in the latter case the process is characterized by diffusion hindrance. A kinetic model of the process with the parameters ensuring adequate mathematical description of the data obtained was suggested.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Jun 15, 2016

References

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