Access the full text.
Sign up today, get DeepDyve free for 14 days.
Runwei Wang, Ling Xu, Lan Zhao, Bin Chu, L. Hu, Chunfeng Shi, G. Zhu, S. Qiu (2005)
Synthesis, characterization, and catalytic activities of mesostructured aluminophosphates assembled with preformed MFI zeolite nanoclustersMicroporous and Mesoporous Materials, 83
S. Mukhopadhyay, and Chandnani, S. Chandalia (2000)
Kinetics of Highly Selective Catalytic Hydrogenation of 2,3,5-Trimethylbenzoquinone on Raney Nickel CatalystOrganic Process Research & Development, 4
Xiangju Meng, Zhenhua Sun, Sen Lin, Miao Yang, Xiao‐Yu Yang, Jianmin Sun, D. Jiang, F. Xiao, Song Chen (2002)
Catalytic hydroxylation of 2,3,6-trimethylphenol with hydrogen peroxide over copper hydroxyphosphate (Cu2(OH)PO4)Applied Catalysis A-general, 236
Runwei Wang, L. Hu, Bin Chu, Lan Zhao, G. Zhu, S. Qiu (2005)
Synthesis, characterization, and catalytic activities of mesostructured titanosilicates assembled from quaternary alkylammonium with preformed titanosilicate precursors under alkaline and acidic conditionsCatalysis Communications, 6
Xiangju Meng, W. Fan, Y. Kubota, T. Tatsumi (2006)
Improvement in thermal stability and catalytic activity of titanium species in mesoporous titanosilicates by addition of ammonium saltsJournal of Catalysis, 244
D. Qian, Ai-hua Shi, Qiyuan Chen, Zhijian Liu (2005)
Thermal behaviors of deactivation catalysts for synthesizing 2, 3, 5-trimethylhydroquinoneJournal of Central South University of Technology, 12
D. Cornwell, Jiyan Ma (2007)
Studies in vitamin E: biochemistry and molecular biology of tocopherol quinones.Vitamins and hormones, 76
A. Azzi (2007)
Molecular mechanism of α-tocopherol actionFree Radical Biology and Medicine, 43
(2009)
Catalytic hydrogenation of TMBQ to TMHQ
K. Sato, Y. Fujima, A. Yamada (1968)
Synthesis of trimethylhydroquinone from p-xylene.Bulletin of the Chemical Society of Japan, 41 2
An efficient and green process of catalytic hydrogenation of 2,3,5-trimethylbenzoquinone (TMBQ) to 2,3,5-trimethylhydroquinone (TMHQ) on Pd/C catalyst using the LBA (a commercial mixed solvent) as solvent is described. The important reaction parameters (e.g. temperature, catalyst loading, initial concentration of TMBQ, hydrogen pressure, and agitation speed) have been investigated to acquire the optimal process conditions. The hydrogenation molar yield of TMHQ by HPLC analysis is 99.4 %. The solvent could be recovered by steam distillation, while the isolated TMHQ overall molar yield reaches up to 96.7 %. The deactivation of Pd/C during the reuse of catalysts was ascribed to the depositions of TMHQ and TMBQ based on various characterizations and regeneration study of catalyst. The possible catalytic hydrogenation mechanism is also discussed.
Research on Chemical Intermediates – Springer Journals
Published: May 1, 2013
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.