Hydroxylation of phenol with hydrogen peroxide in protic and aprotic solvents on TS-1 catalyst

Hydroxylation of phenol with hydrogen peroxide in protic and aprotic solvents on TS-1 catalyst Hydroxylation of phenol with a 25% aqueous solution of hydrogen peroxide in polar protic and aprotic solvents on TS-1 heterogeneous catalyst under various conditions was studied. The major reaction products (hydroquinone, pyrocatechol) and their ratio were determined. A kinetic model describing the hydroxylation in accordance with the Rideal-Eley mechanism was chosen. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Hydroxylation of phenol with hydrogen peroxide in protic and aprotic solvents on TS-1 catalyst

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Publisher
SP MAIK Nauka/Interperiodica
Copyright
Copyright © 2011 by Pleiades Publishing, Ltd.
Subject
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427211040148
Publisher site
See Article on Publisher Site

Abstract

Hydroxylation of phenol with a 25% aqueous solution of hydrogen peroxide in polar protic and aprotic solvents on TS-1 heterogeneous catalyst under various conditions was studied. The major reaction products (hydroquinone, pyrocatechol) and their ratio were determined. A kinetic model describing the hydroxylation in accordance with the Rideal-Eley mechanism was chosen.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: May 19, 2011

References

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