Hydroxyl radical-mediated advanced oxidation processes for textile dyes: a comparison of the radiolytic and sonolytic degradation of the monoazo dye Acid Orange 7

Hydroxyl radical-mediated advanced oxidation processes for textile dyes: a comparison of the... Acid Orange 7, a textile azo dye, has been partially mineralized and degraded using γ-radiolysis and sonolysis. These two different advanced oxidation processes (AOP) are effective in producing ⋅OH radicals and cause complete destruction of the chromophore. The reaction mechanism of dye degradation has been probed by analyzing the reaction products with HPLC. In both cases, the final end products of degradation are oxalate and formate ions. The intermediates observed are all similar. While hydroxybenzenesulfonic acid is the major observed reaction intermediate in the oxidation processes, the pulse radiolysis studies indicate that the OH radical initiated pathway for attack occurs via the initial formation of 1,2-naphthaquinone and subsequent breakdown into oxalic acid. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Hydroxyl radical-mediated advanced oxidation processes for textile dyes: a comparison of the radiolytic and sonolytic degradation of the monoazo dye Acid Orange 7

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Publisher
Brill Academic Publishers
Copyright
Copyright © 2003 by VSP 2003
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1163/156856703764929967
Publisher site
See Article on Publisher Site

Abstract

Acid Orange 7, a textile azo dye, has been partially mineralized and degraded using γ-radiolysis and sonolysis. These two different advanced oxidation processes (AOP) are effective in producing ⋅OH radicals and cause complete destruction of the chromophore. The reaction mechanism of dye degradation has been probed by analyzing the reaction products with HPLC. In both cases, the final end products of degradation are oxalate and formate ions. The intermediates observed are all similar. While hydroxybenzenesulfonic acid is the major observed reaction intermediate in the oxidation processes, the pulse radiolysis studies indicate that the OH radical initiated pathway for attack occurs via the initial formation of 1,2-naphthaquinone and subsequent breakdown into oxalic acid.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Oct 17, 2004

References

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