Hydrotreating of vacuum gasoil in mixture with delayed coking products on industrial NiMo/Al2O3 catalyst

Hydrotreating of vacuum gasoil in mixture with delayed coking products on industrial NiMo/Al2O3... To examine the influence exerted on the degree of hydrogenation and hydrogenolysis by the content of olefin (diolefin) and polycyclic aromatic hydrocarbons at different fractional compositions of distillate mixtures, joint hydrotreating of vacuum gasoil with benzine and light and heavy coking gasoils was performed. The study was carried out in a laboratory installation under a hydrogen pressure of 5.0 MPa, temperature of 375°C, volumetric flow rate of raw materials of 1 h−1, and H2/raw material ratio of 1000/1. The effect of the composition of raw materials and process conditions on the chemical composition and quality parameters of the resulting products was demonstrated. It was shown that a pronounced competition between olefin and polycyclic aromatic hydrocarbons in hydrogenation reactions is observed for mixtures of heavy vacuum gasoil and light coking gasoil, in contrast to mixtures of straight-run diesel fraction and light coking gasoil. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Hydrotreating of vacuum gasoil in mixture with delayed coking products on industrial NiMo/Al2O3 catalyst

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Publisher
Springer Journals
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427215040096
Publisher site
See Article on Publisher Site

Abstract

To examine the influence exerted on the degree of hydrogenation and hydrogenolysis by the content of olefin (diolefin) and polycyclic aromatic hydrocarbons at different fractional compositions of distillate mixtures, joint hydrotreating of vacuum gasoil with benzine and light and heavy coking gasoils was performed. The study was carried out in a laboratory installation under a hydrogen pressure of 5.0 MPa, temperature of 375°C, volumetric flow rate of raw materials of 1 h−1, and H2/raw material ratio of 1000/1. The effect of the composition of raw materials and process conditions on the chemical composition and quality parameters of the resulting products was demonstrated. It was shown that a pronounced competition between olefin and polycyclic aromatic hydrocarbons in hydrogenation reactions is observed for mixtures of heavy vacuum gasoil and light coking gasoil, in contrast to mixtures of straight-run diesel fraction and light coking gasoil.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Jul 14, 2015

References

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