Hydrodynamic, molecular, and conformational characteristics of macromolecules of a random copolymer of N-Methyl-N-vinylacetamide and N-Methyl-N-vinylamine Hydrochloride

Hydrodynamic, molecular, and conformational characteristics of macromolecules of a random... The development and optimization of processes involving polymeric molecules require determination and monitoring of key molecular characteristics of the polymer. Samples of poly-N-methyl-N-vinylacetamide were synthesized and fractionated. Partial hydrolysis of the homopolymer fractions was performed, and fractions of a random copolymer of N-methyl-N-vinylacetamide and N-methyl-N-vinylamine hydrochloride were obtained. The molecular weights and conformational parameters of the homo- and copolymers in 0.2 M aqueous NaCl were determined by methods of molecular hydrodynamics. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Hydrodynamic, molecular, and conformational characteristics of macromolecules of a random copolymer of N-Methyl-N-vinylacetamide and N-Methyl-N-vinylamine Hydrochloride

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Publisher
SP MAIK Nauka/Interperiodica
Copyright
Copyright © 2012 by Pleiades Publishing, Ltd.
Subject
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427212080174
Publisher site
See Article on Publisher Site

Abstract

The development and optimization of processes involving polymeric molecules require determination and monitoring of key molecular characteristics of the polymer. Samples of poly-N-methyl-N-vinylacetamide were synthesized and fractionated. Partial hydrolysis of the homopolymer fractions was performed, and fractions of a random copolymer of N-methyl-N-vinylacetamide and N-methyl-N-vinylamine hydrochloride were obtained. The molecular weights and conformational parameters of the homo- and copolymers in 0.2 M aqueous NaCl were determined by methods of molecular hydrodynamics.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Sep 15, 2012

References

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