Hydrodynamic properties of 10 samples of poly(1-trimethylsilylpropyne) of various molecular weights, obtained with NbCl5 catalyst and containing 60-70% cis C = C bonds, were studied by sedimentation, translation diffusion, and viscometry techniques. The equilibrium rigidity of the polymer molecules was estimated from the viscometric data using the formalism of the intrinsic viscosity theory as applied to the worm-like coil model with excluded-volume effects. For the polymer macromolecules, the Kuhn segment length, thermodynamic parameter ε, and hydrodynamic diameter of the chain d were estimated.
Russian Journal of Applied Chemistry – Springer Journals
Published: Oct 13, 2004
It’s your single place to instantly
discover and read the research
that matters to you.
Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.
All for just $49/month
Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly
Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.
Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.
Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.
All the latest content is available, no embargo periods.
“Hi guys, I cannot tell you how much I love this resource. Incredible. I really believe you've hit the nail on the head with this site in regards to solving the research-purchase issue.”Daniel C.
“Whoa! It’s like Spotify but for academic articles.”@Phil_Robichaud
“I must say, @deepdyve is a fabulous solution to the independent researcher's problem of #access to #information.”@deepthiw
“My last article couldn't be possible without the platform @deepdyve that makes journal papers cheaper.”@JoseServera