Access the full text.
Sign up today, get DeepDyve free for 14 days.
G. Bellussi, M. Rigutto (1995)
Metal Ions Associated to the Molecular Sieve Framework: Possible Catalytic Oxidation SitesChemInform, 26
Z. Tvarłzˇková, K. Habersberger, N. Zˇilkova, P. Jírł (1991)
Role of surface complexes on titanium-silicate in the ammoximation of cyclohexanone with hydrogen peroxideApplied Catalysis A-general, 79
A. Thangaraj, S. Sivasanker, P. Ratnasamy (1991)
Catalytic properties of crystalline titanium silicalites III. Ammoximation of cyclohexanoneJournal of Catalysis, 131
H. Hayashi, J. Somei, T. Okazaki (1988)
Ammonia—Hydrazine conversion processes: XVI. Conversion of benzophenone azine into hydrazine catalyzed by sulphonic acids in a two-phase systemApplied Catalysis, 41
G. Peregot, G. Bellussi, C. Corno, M. Taramasso, F. Buonomot, A. Esposito (1986)
Titanium-Silicalite: a Novel Derivative in the Pentasil FamilyStudies in Surface Science and Catalysis, 28
H. Hayashi, K. Kikawa, Y. Murai, N. Shigemoto, S. Sugiyama, K. Kawashioro (1996)
Competitive oxidation of 1- and 2-propanol catalyzed by titanium silicalite-1 and the application for selective oxidation of 1-methoxy-2-propanol to 1-methoxy-2-propanoneCatalysis Letters, 36
R. Layer (1963)
The Chemistry of Imines.Chemical Reviews, 63
M. Mantegazza, G. Leofanti, G. Petrini, M. Padovan, A. Zecchina, S. Bordiga (1994)
Selective Oxidation of Ammonia to Hydroxylamine with Hydrogen Peroxide on Titanium Based CatalystsStudies in Surface Science and Catalysis, 82
H. Hayashi, K. Kawasaki, M. Fujii, Akihiko Kainoh, T. Okazaki (1976)
Copper-catalyzed oxidative coupling of diphenylmethanimine promoted by some monodentate pyridines☆Journal of Catalysis, 41
M. Mantegazza, A. Cesana, M. Pastori (1996)
Ammoximation of ketones on titanium silicalite. A study of the reaction byproductsTopics in Catalysis, 3
H. Hayashi, Akihiko Kainoh, M. Katayama, K. Kawasaki, T. Okazaki (1976)
Hydrazine Production from Ammonia via AzineIndustrial & Engineering Chemistry Product Research and Development, 15
P. Roffia, G. Leofanti, A. Cesana, M. Mantegazza, M. Padovan, G. Petrini, S. Tonti, P. Gervasutti (1990)
Cyclohexanone Ammoximation: A Break Through In The 6-Caprolactam Production ProcessStudies in Surface Science and Catalysis, 55
H. Hayashi (1990)
Hydrazine Synthesis by a Catalytic Oxidation ProcessCatalysis Reviews-science and Engineering, 32
W. Meier, D. Olson, C. Baerlocher (1988)
Atlas of Zeolite Structure Types
P. Birke, P. Kraak, R. Schödel, F. Vogt (1994)
Carbon Supported TS-1 CatalystsStudies in Surface Science and Catalysis, 83
M. Kapoor, J. Gallot, A. Raj, S. Kaliaguine (1995)
Selective production of hydrazine by a catalytic oxidation process over Ti-, V-, Ti-V- and Ti-B-silicalitesJournal of The Chemical Society, Chemical Communications
R. Kirk, D. Othmer (1998)
Encyclopedia of chemical technology
J. Dunitz (1957)
The crystal structures of copper dipyridine dichloride and the violet form of cobalt dipyridine dichlorideActa Crystallographica, 10
P. Smith (1966)
The chemistry of open-chain organic nitrogen compounds
M. Clerici, P. Ingallina (1993)
Epoxidation of Lower Olefins with Hydrogen Peroxide and Titanium SilicaliteJournal of Catalysis, 140
F. Raschig (1907)
Vorlesungsversuche aus der Chemie der anorganischen StickstoffverbindungenEuropean Journal of Inorganic Chemistry, 40
H. Hayashi, M. Mori, N. Shigemoto, T. Okazaki (1978)
Oxidative Coupling of Diphenylmethanimine Catalyzed by Copper-Loaded Copolymers of 4-Vinylpyridine and DivinylbenzeneIndustrial & Engineering Chemistry Product Research and Development, 17
H. Hayashi, J. Somei, M. Akei, T. Suga, H. Kigami, N. Hiramatsu, H. Itoyama, T. Nakano, T. Okazaki (1991)
Preparation of sulfonated resins as an immobilized phase-transfer catalyst for the hydrolysis of benzophenone azine to hydrazine☆☆☆Journal of Catalysis, 130
J. Schirmann, F. Weiss (1972)
Chimie des peroxydes en milieu basique I - oxydation des bases de schiff en oxaziridines avec le peroxyde d'hydrogene et un nitrileTetrahedron Letters, 13
G. Payne, P. Deming, Paul Williams (1961)
Reactions of hydrogen peroxide. VII. Alkali-catalyzed epoxidation and oxidation using a nitrile as co-reactantJournal of Organic Chemistry, 26
Res. Chem. Intermed, Vol. 24, No. 2, pp. 183-196 (1998) 9 VSP 1998 HYDRAZINE SYNTHESIS: COMMERCIAL ROUTES, CATALYSIS AND INTERMEDIATES HIROMU HAYASHI Department of Chemical Science and Technology, University of Tokushima, Minamijosanjima, Tokushima 770 JAPAN Received 3 September 1997; accepted 18 December 1997 CONTENTS I. Introduction II. Formation of Hydrazine: Publication Statistics and Installed Capacity III. Commercial Routes to Hydrazine: Chemistry and Intermediates Raschig Synthesis (NaOH-CI2-NH3) Schestakov Synthesis (NaOH-C12-Urea) Bayer Process (Ketone-NH3-Cl2) Ugine Kuhkmann (Atochem) Process (Ketone-NH3-H202) IV. Catalytic Oxidation with Molecular Oxygen Chemistry of lmines Copper-Catalyzed Oxidative N-N Coupling: Azine Synthesis a) Copper Complexes b) Monodentate Pyridines c) Active Copper Species d) Structure of Copper Complexes e) Copper-Loaded Polymer Catalysts Recovery of Hydrazine V. Attempted Catalytic Hydrogen Peroxide Oxidation Activation of Hydrogen Peroxide Oxaziridine Intermediate Hydroxylamine Hydrazine VI. Conclusion I. INTRODUCTION Hydrazine is one of the most versatile chemicals, finding use in a wide spectrum of applications such as an energy source in fuel cells and rocket propulsion, synthesis 184 I~ Hayashi of organic nitrogen compounds for medical and agricultural use, a blowing agent for polymers, and an oxygen scavenger for boiler water [1]. Comparing aquo- (H-O-H) and ammono- (H-NH-H) systems, hydrazine (H-NH-NH-H) can be regarded as the
Research on Chemical Intermediates – Springer Journals
Published: Apr 14, 2009
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.