Hirshfeld surface analysis of a Zn(II) polymer

Hirshfeld surface analysis of a Zn(II) polymer A new Zn-based complex with oxalate, namely [NH2(CH3)2][Zn(Ox)1.5] · DMF · H2O (I) (Ox = oxalate), has been synthesized and structurally characterized. Single-crystal X-ray analysis of compound I reveals that the Ox ligand links the Zn(II) center, generating an intricate 2D classical honeycomb-like architecture (CIF file CCDC no. 1028787). The detail analyses of Hirschfeld surface and fingerprint plots gave a mode of non-covalent interactions in the title compound. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Hirshfeld surface analysis of a Zn(II) polymer

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Publisher
Pleiades Publishing
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328415050085
Publisher site
See Article on Publisher Site

Abstract

A new Zn-based complex with oxalate, namely [NH2(CH3)2][Zn(Ox)1.5] · DMF · H2O (I) (Ox = oxalate), has been synthesized and structurally characterized. Single-crystal X-ray analysis of compound I reveals that the Ox ligand links the Zn(II) center, generating an intricate 2D classical honeycomb-like architecture (CIF file CCDC no. 1028787). The detail analyses of Hirschfeld surface and fingerprint plots gave a mode of non-covalent interactions in the title compound.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: May 7, 2015

References

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