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E. Kikuchi, K. Yogo (1994)
Selective catalytic reduction of nitrogen monoxide by methane on zeolite catalysts in an oxygen-rich atmosphereCatalysis Today, 22
M. Iwamoto, H. Yahiro (1994)
Novel catalytic decomposition and reduction of NOCatalysis Today, 22
M. Ogura, S. Hiromoto, E. Kikuchi (1995)
Precious Metal Loaded In/H-ZSM-5 for Low Concentration NO Reduction with Methane in the Presence of Water VaporChemistry Letters, 1995
C. Yokoyama, M. Misono (1994)
Catalytic reduction of nitrogen oxides by propene in the presence of oxygen over cerium ion-exchanged zeolites. II. Mechanistic study of roles of oxygen and doped metalsJournal of Catalysis, 150
M. Iwamoto, N. Mizuno (1993)
NOx Emission Control in Oxygen-Rich Exhaust Through Selective Catalytic Reduction by HydrocarbonProceedings of the Institution of Mechanical Engineers, Part D: Journal of Automobile Engineering, 207
M. Shimokawabe, A. Ohi, N. Takezawa (1992)
Catalytic decomposition of nitrogen dioxide over various metal oxidesApplied Catalysis A-general, 85
Yuejin. Li, J. Armor (1994)
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H. Hamada, Y. Kintaichi, M. Sasaki, T. Ito, M. Tabata (1991)
Selective reduction of nitrogen monoxide with propane over alumina and HZSM-5 zeolite : Effect of oxygen and nitrogen dioxide intermediateApplied Catalysis, 70
C. Yokoyama, M. Misono (1994)
Catalytic reduction of NO by propene in the presence of oxygen over mechanically mixed metal oxides and Ce-ZSM-5Catalysis Letters, 29
M. Iwamoto, A. Hernández, Tetsu Zengyo (1997)
Oxidation of NO to NO2 on a Pt-MFI zeolite andsubsequent reduction of NOx byC2H4 on an In-MFI zeolite: a novelde-NOx strategy in excess oxygenChemical Communications
A. Stakheev, C. Lee, S. Park, P. Chong (1996)
NO2 formation and its effect on the selective catalytic reduction of NO over Co/ZSM-5Catalysis Letters, 38
Hyun Shin, H. Hirabayashi, H. Yahiro, M. Watanabe, M. Iwamoto (1995)
Selective catalytic reduction of NO by ethene in excess oxygen over platinum ion-exchanged MFI zeolitesCatalysis Today, 26
Intermediate addition of reductant (named an IAR method) into a NO+O2 stream between an oxidation catalyst of NO to NO2 and a reduction catalyst of NOx to N2 has been evidenced to be a very effective method to selectively reduce NO to N2 in the presence of excess oxygen. Here Pt-MFI has been employed as an oxidation catalyst, Na-, Mg-, Ca-, Ba-, Zn-and In-MFI have been examined as the reduction catalysts and the reductant was ethene. The combination of Pt-and Zn-MFI was the most effective. The efficiency of ethene, namely the molar ratio of the amount of NO reduced to that of ethene consumed, reached 1.9 and was much higher than 1.4 of conventional reduction on Cu-MFI.
Research on Chemical Intermediates – Springer Journals
Published: Apr 14, 2009
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