Highly disordered silicon-containing carbon from polymethylphenylsiloxane as anode material for lithium-ion batteries: Anomalous behavior in thin layer

Highly disordered silicon-containing carbon from polymethylphenylsiloxane as anode material for... Carbon-enriched glass-like material was produced by pyrolysis of polymethylphenylsiloxane. The physicochemical (examined by X-ray powder diffraction analysis, photoelectron spectroscopy, Raman scattering method, and energy-dispersive X-ray analysis) and electrochemical (examined by galvanostatic/potentiostatic cycling of electrodes in an organic electrolyte) properties of this material make it possible to regard it as a silicon-doped hard carbon. A thin-film electrode made of this material is cardinally different from pasted powder electrodes in the small hysteresis of charge-discharge curves and high reversible and low irreversible capacity with respect to lithium ions. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Highly disordered silicon-containing carbon from polymethylphenylsiloxane as anode material for lithium-ion batteries: Anomalous behavior in thin layer

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Publisher
Pleiades Publishing
Copyright
Copyright © 2016 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427216080048
Publisher site
See Article on Publisher Site

Abstract

Carbon-enriched glass-like material was produced by pyrolysis of polymethylphenylsiloxane. The physicochemical (examined by X-ray powder diffraction analysis, photoelectron spectroscopy, Raman scattering method, and energy-dispersive X-ray analysis) and electrochemical (examined by galvanostatic/potentiostatic cycling of electrodes in an organic electrolyte) properties of this material make it possible to regard it as a silicon-doped hard carbon. A thin-film electrode made of this material is cardinally different from pasted powder electrodes in the small hysteresis of charge-discharge curves and high reversible and low irreversible capacity with respect to lithium ions.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Nov 24, 2016

References

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