High-energy complex copper(II) perchlorate with 1,5-pentamethylenetetrasole as ligand

High-energy complex copper(II) perchlorate with 1,5-pentamethylenetetrasole as ligand Possibility of obtaining an energy-saturated metal complex, copper tetrakis[cyclopentamethylenetetrasol] perchlorate, was studied by reacting copper(II) perchlorate hexahydrate with cyclopentamethylenetetrazol. The composition and structure of the complex were confirmed by elemental analysis and UV, IR, 1H NMR, and ESR spectroscopies. The thermal decomposition of the metal complex synthesized was analyzed and its explosive characteristics and combustion law, as well as the combustion law of a model formulation of a composite solid propellant with addition of the complex, were determined. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

High-energy complex copper(II) perchlorate with 1,5-pentamethylenetetrasole as ligand

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Publisher
Nauka/Interperiodica
Copyright
Copyright © 2007 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427207100060
Publisher site
See Article on Publisher Site

Abstract

Possibility of obtaining an energy-saturated metal complex, copper tetrakis[cyclopentamethylenetetrasol] perchlorate, was studied by reacting copper(II) perchlorate hexahydrate with cyclopentamethylenetetrazol. The composition and structure of the complex were confirmed by elemental analysis and UV, IR, 1H NMR, and ESR spectroscopies. The thermal decomposition of the metal complex synthesized was analyzed and its explosive characteristics and combustion law, as well as the combustion law of a model formulation of a composite solid propellant with addition of the complex, were determined.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Nov 24, 2007

References

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