www.nature.com/scientificreports OPEN Hexagonal MoTe with Amorphous BN Passivation Layer for Improved Oxidation Resistance and Endurance Received: 25 January 2018 of 2D Field Effect Transistors Accepted: 18 May 2018 Published: xx xx xxxx 1 2 3,4 4 Benjamin Sirota , Nicholas Glavin , Sergiy Krylyuk , Albert V. Davydov & Andrey A. Voevodin Environmental and thermal stability of two-dimensional (2D) transition metal dichalcogenides (TMDs) remains a fundamental challenge towards enabling robust electronic devices. Few-layer 2H-MoTe with an amorphous boron nitride (a-BN) covering layer was synthesized as a channel for back-gated field effect transistors (FET) and compared to uncovered MoTe . A systematic approach was taken to understand the effects of heat treatment in air on the performance of FET devices. Atmospheric oxygen was shown to negatively affect uncoated MoTe devices while BN-covered FETs showed considerably enhanced chemical and electronic characteristic stability. Uncapped MoTe FET devices, which were heated in air for one minute, showed a polarity switch from n- to p-type at 150 °C, while BN-MoTe devices switched only after 200 °C of heat treatment. Time-dependent experiments at 100 °C showed that uncapped MoTe samples exhibited the polarity switch after 15 min of heat treatment while the BN-capped device maintained its n-type conductivity for the maximum 60 min duration of the experiment. X-ray photoelectron spectroscopy (XPS) analysis suggests that oxygen incorporation into MoTe was the primary doping mechanism for the polarity switch. This work demonstrates the effectiveness of an a-BN capping layer in preserving few-layer MoTe material quality and controlling its conductivity type at elevated temperatures in an atmospheric environment. Recent advances in the field of 2D materials have focused on molecular-thin, TMDs as semiconductor counterparts 1–5 to graphene in the use of nanoscale electronics . One such TMD is MoTe , which oe ff rs a unique combination of a semiconductor (hexagonal 2 H polytype) to metal (trigonal 1 T′ polytype) phase transition, indirect-to-direct bandgap transition in low-dimensional limits, spin-orbit coupling, strong photoluminescence response, and high 6–9 transistor on/off ratios . Monolayer 2H-MoTe has a direct band gap of 1.10 eV, which transitions to an indirect band gap of 0.81 eV for bulk MoTe as the layer number increases . The charge carrier quantum confinement, high mobility, and reduced interaction with adjusted layers due to a lack of dangling surface bonds has initiated an extensive number of studies regarding monolayer TMDs for electrical and optoelectronic devices. In this respect, 11,12 13 14 field effect transistors made of 2D MoTe have been demonstrated to exhibit p-type , n-type , and ambipolar behavior. MoTe FETs have been reported to have on/off ratios above 10 , subthreshold swing of 140 mV/dec, and 2 −1 11 Hall mobilities around 10 cm (V s) . Such properties with an interesting ability for ambipolar behavior suggest monolayer 2H-MoTe can be attractive for semiconducting devices as compared to other 2D TMDs. A major hindrance of many 2D TMDs is their limited stability in air, especially when they are subjected to moderate heating during processing or device operation. While the perfect TMD monolayers are relatively stable, the presence of defects, such as point defects and edges of single crystal domains, play a decisive role in deter- mining the stability of 2D TMDs when exposed to an oxidizing environment. Oxygen substitution of chalcogen atoms and oxidation along the crystal edges are the most commonly reported culprits for the deterioration of 15,16 charge confinement and transport characteristics of 2D TMDs . From this perspective, the packaging of 2D Department of Materials Science and Engineering, Advanced Materials and Manufacturing Processing Institute, University of North Texas, Denton, TX, 76203, USA. Materials and Manufacturing Directorate, Air Force Research 3 4 Laboratory, Wright-Patterson AFB, OH, 45433, USA. Theiss Research, Inc, La Jolla, CA, 92037, USA. Materials Science and Engineering Division, National Institute of Standards and Technology, Gaithersburg, MD, 20899, USA. Correspondence and requests for materials should be addressed to A.A.V. (email: Andrey.Voevodin@unt.edu) ScIEntIFIc REPO R TS | (2018) 8:8668 | DOI:10.1038/s41598-018-26751-4 1 www.nature.com/scientificreports/ Figure 1. (a) An optical image of an MoTe exfoliated flake on SiO /Si substrate: the few-layer section can be 2 2 identified by the dark green color while the bulk is a lighter blue-green. (b) AFM image and line scan (dashed black line) from the few-layer section of flake in 1a: the height profile from the line scan measures a difference of 2.30 nm, which corresponds to 3 monolayers of MoTe . (c) The Raman spectrum from MoTe flake, which is in 2 2 agreement with few-layer MoTe . TMDs layers within electrically insulating and dielectric (for FET applications) thin layers, which can also prevent oxidation and deterioration of 2D TMD characteristics, is of a significant practical interest to advance 2D TMDs for device applications. The challenge of such passivation layers is in avoiding interaction of the 2D TMD layers with the adjusted electrically insulating materials, where typical thin dielectrics are mostly based on oxides (e. g., SiO , Al O , HfO ), which intrinsically bring oxygen atoms in contact with TMDs and can contribute to TMD 2 2 3 2 deterioration. This becomes especially prevalent if elevated temperatures are encountered during dielectric layer deposition or device operation. Thus, an exploration of a non-oxide based and environmentally stable dielectric material to be used in conjunction with TMD FET devices, or other 2D materials such as graphene and black phosphorus, and would benefit the wider usage of such materials. Boron nitride has emerged as a dielectric counterpart to TMDs due to its chemical stability, lack of dangling bonds, and wide bandgap (5.97 eV) characteristics . Most notably, hexagonal boron nitride (h-BN), which has a similar crystal structure to graphene , can be exfoliated onto various 2D materials to form heterostructures 19–21 22 23 24 25 such as h-BN-MoS , h-BN-WS , h-BN-MoSe , and BN-WSe -BN with remarkable electrical properties . 2 2 2 2 While these studies clearly demonstrate the benet fi of h-BN packaging with TMD for improved mobility, on/o ff ratio, and thermal management, the challenge of exfoliation routes for such 2D heterostructure device assemblies is prohibitive for the scalable and cost-ee ff ctive device production, leading to the search of alternative routes for h-BN synthesis and integration with TMD structures . Deposition of h-BN layers via chemical vapor deposition 26–29 routes have been extensively explored but require high temperatures during synthesis and annealing , reduc- ing applicability for temperature sensitive TMDs. Most recently, research involved in physical vapor deposition (PVD) of BN thin films has demonstrated the advantage of room temperature growth of amorphous BN (a-BN) layers on the order of 2 nm to 3 nm thickness over large areas, which show a bandgap of 4.5 eV, dielectric constant of about 6 and breakdown voltage on the 30,31 order of 10 MV/cm . This makes them comparable to exfoliated h-BN for dielectric applications. Passivation 32 33 layers of PVD-grown a-BN in combination with graphene , 2D WS and MoS , have shown improved field 2 2 effect mobility and reduced background charge carrier concentration. Herein, we investigate devices composed of exfoliated 2 H MoTe with a PVD-grown a-BN passivation layer to study chemical and structural stability of 2D MoTe at elevated temperatures. The studies also include an analysis of FET device performance (including n- to p-type behavior transition, on/off ratio, and carrier mobility) aer h ft eating in air, covering a possible range of temperatures of such 2H-MoTe /a-BN device applications in electronic devices. Formation of Te vacancy sites and the potential for atmospheric oxygen to form substitutional dopants were of critical attention in the per- formed study. We find this BN capping layer to be an effective barrier layer, which protects the 2D TMD material from detrimental chemical oxidation, and significantly reduces the rate of field ee ff ct mobility and on/off ratio degradation of FET devices as compared to the uncapped sample. Results and Discussion Material exfoliated and characterization. Figure 1a depicts an optical image of an exfoliated 2H-MoTe flake. The optical contrast of few layers and bulk flakes on SiO /Si substrates provides a good guide to the flake thickness, since it is known that 2D flakes that contain one to few layers show a darker optical color than bulk material due to altering optical contrast with the SiO /Si substrate . AFM from a non-contact scan is shown in Fig. 1b, demonstrating good thickness uniformity of the dark-green area from Fig. 1a. A line scan measures a height difference of 2.30 nm, which corresponds to tri-layer MoTe . The Raman spectrum in Fig. 1c, clearly −1 −1 −1 1 shows three distinct peaks typical for MoTe at 170 cm , 235 cm and 289 cm , corresponding to the A , E 2 1g 2g and B phonon modes, respectively . The A mode is due to out-of-plane phonon vibrations and is typically 2g 1g 37 1 weak for 532 nm laser excitations . The E peak is the dominant mode and corresponds to in-plane atomic 2g oscillations, and it has been shown to exhibit a strong signal for MoTe in the 2D form and is relatively weak for bulk material . The B mode corresponds to the out-of-plane interaction of adjacent layers and has an interest- 2g ing property in which it is clearly present for 2 to 5 of MoTe layers but absent for either monolayer or the bulk thickness. This peak was reported to have its strongest value for 2 layers and rapidly decreasing as the thickness ScIEntIFIc REPO R TS | (2018) 8:8668 | DOI:10.1038/s41598-018-26751-4 2 www.nature.com/scientificreports/ Figure 2. (a) Raman spectra of the E peak intensity variation for few monolayers thick 2H-MoTe flakes 2g 2 exposed to 100 °C in air for the shown time intervals. (b) Comparison of E peak intensities changes as 2g a function of 100 °C in air holding time for uncapped MoTe and BN-capped MoTe flakes; to facilitate 2 2 the comparisons and avoid errors due to absolute peak intensity changes over time, the peak intensity was −1 1 normalized to the Si substrate peak (520.5 cm ). The shown linear fitting was used to calculate E peak 2g intensity decline due to oxidation processes for 2H-MoTe and 2H-MoTe /a-BN. 2 2 34 1 increases until it disappears aer 5 l ft ayers . Therefore, the relative intensities of the E and B peaks can be used 2g 2g to determine layer thickness and verify AFM measurements as presented in Fig. 1b. For all MoTe flakes selected for this study, the Raman spectra displayed a strong E peak and less intense A and B peaks, which is in agree- 2g 1g 2g ment with 3-layer thickness measurements with AFM (Fig. 1c). In order to analyze the 2D MoTe thermal degradation rate over time, Raman spectra comparing the 2H-MoTe 2 2 E mode for samples heated at 100 °C for up to 60 min with 10 min increment were collected and are shown in 2g Fig. 2a. Gauss peak fitting of the E mode had determined that this vibration mode maintains its location at 2g −1 ≈234 cm throughout the experiment, which suggests the 2H-MoTe did not undergo a thickness change aer ft 60 min of 100 °C heat treatment in air. However, the E peak exhibits a continuous intensity decline from its max 2g value at room temperature, and the rate of this decline is strongly ae ff cted by the presence of the BN cap layer. e Th Raman analysis did not show the presence of MoO or MoO vibration modes for both uncapped and a-BN 3 2 capped 2H-MoTe flakes, suggesting that no individual phases of molybdenum oxide crystal structure was formed. However, XPS analysis discussed below shows that heating in air had resulted in surface oxidation. Normalizing 1 −1 the E peaks to the Raman peak of silicon at 520 cm allows for comparison between uncapped and BN capped 2g flakes. Figure 2b clearly shows that the uncapped MoTe exhibits a much greater rate of decay of the E Raman 2 2g mode. Such is likely brought by damping the inter-layer oscillation modes with increased lattice imperfections and internal atomic stresses from Te vacancies and oxygen substitutions. In contrast, normalized Raman spectra of the BN-capped MoTe sample maintained its E peak intensity after 60 min of heating, see Supplementary 2 2g data Figure S1. Applying a linear fit to the data, the slopes of the fitting lines suggest that the decay rate for the E mode in 2H-MoTe material with 100 °C exposure time is an order of magnitude higher than that for the 2g 2 −3 −1 −4 −1 2H-MoTe /a-BN, (8.3 × 10 min versus 8.1 × 10 min , respectively). The results clearly demonstrated the benefit of the BN capping layer for the preservation of 2H-MoTe structure at elevated temperatures in air. In order to investigate in more detail, the chemical state changes of MoTe aer exp ft osure to elevated temper - atures in air, XPS analysis was conducted on exfoliated flakes with and without BN layers aer h ft eating at 100 °C for 60 min. The results are presented in Fig. 3, and XPS spectra of MoTe flakes before heating can be found in Supplemental Figure S2. The uncoated MoTe flake shows three distinct peaks for the Mo 3d orbital, which can be seen in the top spectrum of Fig. 3a. The recorded spectra deconvolutions with 3d doublets reveal a clear presence of two chemical states with Mo 3d peak locations at 234.6 eV and 231.5 eV. The higher binding energy doublet 3/2 6+ 4+ 38 belongs to Mo in MoO bonding, and the lower one to Mo in MoTe . This suggests partial oxidation of the 3 2 MoTe surface. In a sharp contrast, similar analysis of the MoTe /BN sample aer 60 ft min exposure to 100 °C in air 2 2 shows only one doublet with Mo 3d peak location at 231.4 eV, indicating the absence of molybdenum oxidation 3/2 when the BN capping layer was applied. Similar observation of the BN-capping layer preventing oxidation can be made from corresponding XPS spectra of Te 3d, shown in Fig. 3b. The un-capped MoTe (upper spectrum) has dominant Te-O peaks at 575.92 eV and 586.42 eV, corresponding to TeO formation. On the other hand, the BN-capped (lower spectrum) sample has dominant peaks at 572.9 eV and 583.4 eV and significantly weaker Te-O peaks at 576.3 eV and 586.8 eV. This suggests that heating of the uncapped MoTe in air results in possible oxida- tion as evidenced by the appearance of Mo-O and Te-O bonds in the XPS spectra. This process was significantly suppressed for the MoTe /BN sample. The XPS analysis corroborate the Raman studies that the application of the 10 nm thin BN layer can effectively resist oxidation of MoTe at elevated temperatures in air. Electrical Measurements of Uncapped and BN-capped devices. T o determine the ee ff ct of an a-BN capping layer on the retaining charge transport characteristics and MoTe based FET device performance upon exposure to elevated temperature in air back-gated FET devices were fabricated from few-layer thick MoTe flakes on SiO 2 2 ScIEntIFIc REPO R TS | (2018) 8:8668 | DOI:10.1038/s41598-018-26751-4 3 www.nature.com/scientificreports/ Figure 3. XPS analysis of the (a) Mo 3d and (b) Te 3d binding energies for 2H-MoTe and 2H-MoTe /a-BN 2 2 flakes aer 60 ft minutes of 100 °C heating. The BN-capped sample maintains its Mo-Te bonding, demonstrating increased resistance to oxidation, while the appearance of Mo-O and Te-O bonds in the uncapped device suggests significant oxidation of MoTe to form MoO and TeO phases. 2 3 2 using electron beam lithography. This amorphous BN layer was previously determined to be pin-hole free dielec- tric material with breakdown characteristic and dielectric constant exceeding CVD grown h-BN films, approach- 30,31 ing that of mechanically exfoliated h-BN . Such deposition method is ideal for a cost-effective application of dielectric BN layer for 2D heterostructures as compared with other 2D BN growth methods . In the recent stud- ies of PLD grown amorphous BN it was found that the dielectric properties were close to that of h-BN and be as smooth as underlying substrates, where graphene, MoS , WS and a variety of metal and ceramic substrates were 2 2 2 30,31,39 tested with an equal result in a-BN smoothness and pin-hole free morphology over several cm areas . While there were no systematic studies to determine a-BN inertness, the earlier explorations with a-BN/graphene het- erostructures had shown a significant increase of mobility in graphene monolayers when it was sandwiched with a-BN, relating this to a-BN inertness, similar to monolayer thin h-BN . Stabilization of charge transport charac- 40,41 teristics of epitaxially grown graphene in air by the application of a capping a-BN layer was also reported . We then reasonably expected a similar effect with MoTe devices, and such is explored for the first time in this study at elevated temperatures in air. Back-gated FET device schematic made from MoTe and including a BN capping layer is depicted in Fig. 4a and an example of such fabricated device is shown in an optical image of Fig. 4b. Electrical performance of back-gated FET devices annealed from room temperature to 300 °C is shown in Fig. 4. MoTe /BN and MoTe as-exfoliated devices underwent the side by side elevated temperature in air expo- 2 2 sure and were held for 1 min at the target temperature in atmospheric conditions before cooling down and meas- uring their performance. Figure 4c presents a semi-log plot of drain current (I ) versus gate voltage (V ) for a dc g MoTe device as the annealing temperature was systematically increased from room temperature to 300 °C at 50 °C increments. The device initially exhibits n-type behavior as indicated by the positive slope, with the max- imum current decreasing slightly as the temperature is increased to 100 °C. At 150 °C (pink curve) the polarity switches to p-type behavior as indicated by the negative slope. At 200 °C, the device operates as a p-type but also exhibits semi-metallic behavior as indicated by the linear slope. For few-layer materials, this temperature is suf- ficient to sublime Te directly into the vapor state, leaving behind Mo atoms which would contribute to metallic properties. A semi-log I - V plot for a MoTe /BN device is presented in Fig. 4d. The drain current curve remains very dc g 2 stable up to 100 °C. At 150 °C there is a sharp decline in current, however the device remains n-type, as indicated by the drain current curve slope for positive gate voltages. However, after heat treatment at 200 °C, the drain current switches to negative gate voltages and decreases for positive gate voltages, indicating a switch to p-type semiconductor operation. Once temperatures reached 250 °C we noticed the channel lost semiconductor prop- erties and was unresponsive to gate voltage variation, which suggests degradation of MoTe . At 300 °C, the Ti/Au contacts themselves failed and further temperature increase was not performed. Scanning electron microscopy studies of the contacts had shown dewetting of these thin metal films (Supplementary data Figure S3), resulting in a failure of conductive pathways. Such dewetting is expected for thin electrode materials due to the low melting point of gold, and experiments at higher temperatures may require other electrode materials. ScIEntIFIc REPO R TS | (2018) 8:8668 | DOI:10.1038/s41598-018-26751-4 4 www.nature.com/scientificreports/ Figure 4. (a) Schematic cross-section of FET back-gated device with BN capped MoTe . (b) Optical image of typical MoTe few-layer flake with Ti/Au source drain contacts deposited by EBL. (c) Examples of drain current measurements as a function of gate voltage for a backdated MoTe device. The drain voltage was maintained at 1 VDC. Uncovered MoTe device shows initial n-type semiconducting behavior that switches to p-type aer ft 150 °C. (d) The BN/MoTe device maintains a much greater degree of stability through 100 °C and exhibits a polarity switch to p-type behavior much later at 200 °C. 23 °C 50 °C 100 °C 150 °C 200 °C MoTe /BN 1.077, n-type 0.870, n-type 0.837, n-type 0.204, n-type 0.442, p-type MoTe 0.235, n-type 0.157, n-type 0.103, n-type 0.133, p-type 0.212, p-type Table 1. Mobility of uncapped (MoTe ) and BN-capped (BN/MoTe ) devices as a function of temperature with 2 2 2 −1 carrier type. Values were calculated from data in Fig. 4. Mobility units are in cm (V s) . Field effect mobility was calculated from the I - V curves and is shown at various annealing temperatures dc g in Table 1. Before performing any temperature exposure, the measurements of as fabricated devices (23 °C in Table 1) clearly indicate that the capping MoTe with BN has a significant ee ff ct on the mobility improvement as the measured values for MoTe /BN devices were five times greater than that of uncapped MoTe . The abso- 2 2 2 − lute values of the room temperature mobility measurements in the literature vary between 0.03 and 20 cm V 1 −1,11,12,14,42,43 s . While our results are within this reported range, our study demonstrates the effect of a-BN capping layer on the device stability during heating as discussed below. 2 −1 e fie Th ld-effect mobility of BN capped MoTe (red) is maintained around 0.8–1 cm (V s) until 150 °C where 2 −1 it experiences a sharp drop to 0.2 cm (V s) . Furthermore, aer 200 ft °C the mobility values are shown to switch polarity from n- to p-type. The un-coated MoTe in contrast, has a much lower initial mobility and undergoes its polarity switch already at 150 °C. Finally, at 200 °C the mobility absolute value increases slightly. The switch from initial n-type behavior to p-type can be linked to the oxygen incorporation in MoTe layers found from XPS studies (Fig. 3). Previous reports of DFT simulations of oxygen interactions with MoTe and formation of Mo-O and Te-O bonds can lead to the formation of deep-level trap states located 0.4 eV below the conduction band minimum . Such states may act as acceptor sites, effectively resulting in a switch to the p-type behavior as the number of oxygen substitutes for tellurium in MoTe lattice is increased at higher temperatures in air. This is further supported by the delayed polarity switching of our experiments with BN covered device which protects MoTe from oxygen diffusion and subsequent substitution in Te sites. To study the effects of the BN layer for improved endurance of MoTe device characteristics in oxidizing envi- ronments, the FET devices were held at a constant temperature of 100 °C for incrementally increased times from 5 min to up to one hour. I -V curves displaying the change in electrical properties of MoTe and MoTe /BN over dc g 2 2 increased time of exposure to 100 °C in air are displayed as semi-log plots in Fig. 5a,b, respectively. e un Th capped ScIEntIFIc REPO R TS | (2018) 8:8668 | DOI:10.1038/s41598-018-26751-4 5 www.nature.com/scientificreports/ Figure 5. Current-voltage measurements of (a) MoTe and (b) BN/MoTe back-gated FET devices, which were 2 2 held at 100 °C in air for consecutive time increments as shown in data labels. The drain voltage was maintained at 1 VDC. (c) Mobility of MoTe and MoTe /BN devices, shown as a ratio to their initial mobility and plotted 2 2 as a function of the time for device exposure to 100 °C in air. Aer 30 ft minutes, the electron mobility of the uncapped MoTe device had dropped below the measurement noise level and thus is not continued in the plot. (d) Semilog plot comparing on/off ratios of MoTe and MoTe /BN devices. The BN-coated device maintains a 2 2 significantly higher ratio throughout the experiment while the uncapped devices rapidly decreases. MoTe devices (Fig. 5a) exhibit a signic fi ant decrease in maximum drain current ae ft r the first 5 minutes, suggest- ing that the surface oxidation occurs almost immediately. Initially the device is active in the positive gate voltage region, indicating n-type behavior. However, as the heating time increases, the maximum drain currents decrease and transitions to the negative gate voltage region, indicating p-type behavior. Along this n- to p-type transition (about 10–15 min) the devices exhibit ambipolar behavior. For MoTe /BN devices, (Fig. 5b), the maximum drain current also declines with greater heating times but more steadily and remains non-zero even after 60 minutes exposure to 100 °C in air. In addition, the MoTe /BN devices do not undergo a polarity switch to p-type and never lose the n-type behavior (Fig. 5b). In Fig. 5c, the field effect mobility determined aer h ft eating to 100 °C in air is plotted to investigate MoTe FET device endurance and the protective effect of the a-BN capping layer. The initial (before heating to 100 °C in air) values for electron-based mobility were used to normalize the data plot in order to demonstrate the rate of change of the device performance over time. Both MoTe and MoTe /BN devices undergo a rapid mobility decline relative 2 2 to their initial mobility aer fir ft st 10 minutes before leveling off at 20 min to 60 min, suggesting that surface changes to MoTe occur very quickly. The uncapped MoTe devices show a larger decline in field effect mobility compared 2 2 to MoTe /BN devices. In addition, the MoTe /BN devices retain their n-type performance over the entire test 2 2 period without failing, confirming that the a-BN capping is a good choice for improving long-term device perfor - mance in addition to the improved overall mobility values discussed earlier. The on/off ratio change with exposure to 100 °C in air is presented in Fig. 5d. The MoTe /BN device maintains a significantly higher ratio of around 10 throughout the entire 60 min experiment time, while the on/off ratio for uncapped MoTe device rapidly decreases. In conclusion, durability of future 2D TMD devices will rely on solutions to prevent material degradation during their fabrication and operation. Moderate heating of uncapped exfoliated 2H-MoTe in air shows a con- siderable oxidation of few-layer thick MoTe surface resulting in deterioration of the FET device performance. The oxidation can be substantially mitigated by capping the 2H-MoTe with a 10 nm thick a-BN layer, applied by pulsed laser deposition. For uncapped 2H-MoTe , the temperature induced oxidation leads to MoTe struc- 2 2 tural defects with oxygen incorporation and appearance of Mo-O and Te-O bonding in XPS spectra. However, the absence of MoO structure in the Raman data signals that partial oxidation occurred in the form of oxygen defects in Te vacancy sites or physio-absorption to Te surface sites. This is accompanied by the reduction in the field effect mobility and an eventual switch from an n- to p-type semiconductor behavior at around 150 °C. ScIEntIFIc REPO R TS | (2018) 8:8668 | DOI:10.1038/s41598-018-26751-4 6 www.nature.com/scientificreports/ Devices consisting of 2H-MoTe with an a-BN passivation layer were shown to have improved field effect mobility characteristics and significantly suppress material degradation via oxidation from heating in air. For fabricated MoTe /BN FET devices, the oxidation induced polarity switch was delayed to a temperature of 200 °C and as such, retained their n-type mobility and stabilized on/o ff ratio in extended exposure to 100 °C in air. Hence, amorphous BN was found to be an effective approach for preventing 2H-MoTe oxidation and improving the 2D FET device endurance and overall performance. Considering a large area scalability, room temperature growth and versatility of the PLD produced a-BN passivation layer, the explored 2H-MoTe /a-BN structures can be beneficial for elec- tronic and optoelectronic device applications. Methods Preparation of 2H-MoTe . 2H-MoTe single-crystals were produced by the chlorine-assisted chemical 2 2 vapor transport (CVT) method. In brief, a vacuum-sealed quartz ampoule with polycrystalline MoTe powder and a small amount of TeCl (4 mg/cm ) was placed in a furnace containing a temperature gradient so that the MoTe charge was kept at 800 °C, and the temperature at the opposite end of the ampoule was about 710 °C. The ampoule was slowly cooled aer 7 d ft ays of growth. The 2 H phase of the obtained MoTe flakes was confirmed by powder X-ray diffraction and transmission electron microscopy studies. MoTe Device Fabrication. 2H-MoTe flakes were then later mechanically exfoliated onto heavily p-doped 2 2 silicon wafers with a 270 nm silicon oxide surface layer using conventional adhesive tape methods, the details of which have been reported previously . Candidate 2D flakes were identified using optical microscopy since the SiO /Si substrate provides a clear optical contrast for single, double, and few-layer flakes compared to bulk . Flake thickness was estimated using Raman spectroscopy and further confirmed using atomic force microscopy (AFM). Back-gated FETs with channel widths of 2 µm were fabricated by evaporating Ti/Au (20 nm/20 nm) con- tacts onto the MoTe flakes defined by electron beam lithography (EBL) and lift-o. ff a-BN Deposition. Some of the devices were covered, post device fabrication, by an ultrathin amorphous BN layer. This a-BN capping layer of 10 nm thickness, was deposited by pulsed laser deposition using a BN target (99.999%), ablated with a focused 248 nm KrF laser in nitrogen background gas under processing parameters 30,39 optimized for a fully dense, pin-hole free, and stoichiometric BN film growth as reported previously . The a-BN capping layer growth covered the entire device and was deposited at room temperature. We did not notice an effect to the crystallinity of the MoTe or deposited Ti/Au electrodes. Electrical Measurements of Heated Devices. The electrical measurements were performed using an Agilent B2902A system equipped with a probe station. The 10 nm a-BN layer was completely pierced by the con- tact probes to make good metal contact with source and drains electrodes of the devices. Heat treatment experiments were conducted using a hotplate in laboratory air of about 50% relative humidity. Two sets of heating experiments were performed: i) temperature dependent measurements where samples were heated from room temperature (≈23 °C) to 300 °C with a 50 °C increment and held for 1 min before cooling, and ii) time dependent measurements where samples were held at 100 °C with 5-min time increments up to 60 min before cooling down. Back-gated FET devices with both open and a-BN-capped MoTe surfaces were heated simultaneously to ensure experimental consistency. Before taking I-V characteristics, the devices were allowed to cool to room temperature to prevent thermal effects on the measured results and allow direct comparisons of device performances aer h ft eat treatment. References 1. Geim, A. K. & Grigorieva, I. V. Van der Waals heterostructures. Nature 499(7459), 419–25 (2013). 2. Akinwande, D., Petrone, N. & Hone, J. Two-dimensional flexible nanoelectronics. Nat Commun 5, 5678 (2014). 3. Fiori, G. et al. Electronics based on two-dimensional materials. Nature nanotechnology. 9(10), 768–79 (2014). 4. Ganatra, R. & Zhang, Q. Few-layer MoS2: a promising layered semiconductor. ACS nano. 8, 4074–99 (2014). 5. Bhimanapati, G. R. et al. Recent advances in two-dimensional materials beyond graphene. ACS Nano. 9(12), 11509–11539 (2015). 6. Lezama, I. G. et al. Indirect-to-direct band gap crossover in few-layer MoTe(2). Nano Lett 15(4), 2336–42 (2015). 7. Cho, S. et al. Phase patterning for ohmic homojunction contact in MoTe2. Science 349(6248), 625–8 (2015). 8. Qi, Y. et al. Superconductivity in Weyl semimetal candidate MoTe2. Nat Commun 7, 11038 (2016). 9. Sankar, R. et al. Polymorphic Layered MoTe2 from Semiconductor, Topological Insulator, to Weyl Semimetal. Chemistry of Materials 29(2), 699–707 (2017). 10. Keum, D. H. et al. Bandgap opening in few-layered monoclinic MoTe2. Nature Physics 11(6), 482–486 (2015). 11. Pradhan, N. R. et al. Field-effect transistors based on few-layered α-MoTe2. ACS Nano. 8(6), 5911–20 (2014). 12. Fathipour, S. et al. Exfoliated multilayer MoTe2 field-effect transistors. Applied Physics Letters 105(19) (2014). 13. Ji, H. et al. Suppression of Interfacial Current Fluctuation in MoTe2 Transistors with DifferentDielectrics. ACS Appl. Mater. Interfaces 8(29), 19092–9 (2016). 14. Nakaharai, S., Yamamoto, M., Ueno, K. & Tsukagoshi, K. Carrier Polarity Control in alpha-MoTe2 Schottky Junctions Based on Weak Fermi-Level Pinning. ACS Appl Mater Interfaces 8(23), 14732–9 (2016). 15. Zhou, H. et al. Thickness-dependent patterning of MoS2 sheets with well-oriented triangular pits by heating in air. Nano Research. 6(10), 703–711 (2013). 16. Nan, H. et al. Strong photoluminescence enhancement of MoS2 through defect engineering and oxygen bonding. ACS Nano. 8(6), 5738–45 (2014). 17. Pakdel, A., Bando, Y. & Golberg, D. Nano boron nitride flatland. Chem Soc Rev 43(3), 934–59 (2014). 18. Dean, C. R. et al. Boron nitride substrates for high-quality graphene electronics. Nature nanotechnology. 5(10), 722–726 (2010). 19. Lee, G. H. et al. Flexible and transparent MoS2 field-ee ff ct transistors on hexagonal boron nitride-graphene heterostructures. ACS nano. 7(9), 7931–7936 (2013). 20. Wang, S., Wang, X. & Warner, J. H. All chemical vapor deposition growth of MoS2: h-BN vertical van der Waals heterostructures. ACS nano. 9(5), 5246–5254 (2015). ScIEntIFIc REPO R TS | (2018) 8:8668 | DOI:10.1038/s41598-018-26751-4 7 www.nature.com/scientificreports/ 21. Yan, A. et al. Direct Growth of Single- and Few-Layer MoS2 on h-BN with Preferred Relative Rotation Angles. Nano Lett 15(10), 6324–31 (2015). 22. Iqbal, M. W. et al. High-mobility and air-stable single-layer WS2 field-effect transistors sandwiched between chemical vapor deposition-grown hexagonal BN films. Sci Rep 5, 10699 (2015). 23. Zhang, Q. et al. Bandgap renormalization and work function tuning in MoSe2/hBN/Ru(0001) heterostructures. Nat Commun 7, 13843 (2016). 24. Xu, S. et al. High-quality BN/WSe2/BN heterostructure and its quantum oscillations. Preprint at http://arxiv.org/abs/1503.08427 (2015). 25. Bhimanapati, G. R., Glavin, N. R. & Robinson, J. A. In 2D Materials 1st ed, Vol 95 (eds Iacopi, F., Boeckl, J. J. & Jagadish, C.) Ch. 3 (Elsevier, 2016). 26. Song, L. et al. Large scale growth and characterization of atomic hexagonal boron nitride layers. Nano Lett 10(8), 3209–15 (2010). 27. Ismach, A. et al. Toward the controlled synthesis of hexagonal boron nitride films. Acs Nano. 6(7), 6378–6385 (2012). 28. Shi, Y . et al. Synthesis of few-layer hexagonal boron nitride thin film by chemical vapor deposition. Nano letters. 10(10), 4134–4139 (2010). 29. Bresnehan, M. S. et al. Prospects of direct growth boron nitride films as substrates for graphene electronics. Journal of Materials Research. 29, 459–471 (2013). 30. Glavin, N. R. et al. Synthesis of few-layer, large area hexagonal-boron nitride by pulsed laser deposition. in Th Solid Films 572, 245–250 (2014). 31. Glavin, N. R. et al. Amorphous Boron Nitride: A Universal, Ultrathin Dielectric For 2D Nanoelectronics. Advanced Functional Materials 26(16), 2640–2647 (2016). 32. Uddin, M. A. et al. Mobility enhancement in graphene transistors on low temperature pulsed laser deposited boron nitride. Applied Physics Letters 107(20) (2015). 33. McConney, M. E. et al. Direct synthesis of ultra-thin large area transition metal dichalcogenides and their heterostructures on stretchable polymer surfaces. Journal of Materials Research 31(07), 967–974 (2016). 34. Yamamoto et al. Strong enhancement of Raman scattering from a bulk-inactive vibrational mode in few-layer MoTe2. ACS Nano. 8(4), 3895–3903 (2014). 35. Puotinen, D. & Newnham, R. E. The crystal structure of MoTe2. Acta Crystallographica. 14(6), 691–692 (1961). 36. Goldstein, T. et al. Raman scattering and anomalous Stokes-anti-Stokes ratio in MoTe2 atomic layers. Sci Rep. 6, 28024 (2016). 37. Ruppert, C., Aslan, O. B. & Heinz, T. F. Optical properties and band gap of single- and few-layer MoTe2 crystals. Nano Lett. 14(11), 6231–6 (2014). 38. Vishwanath, S. et al. MBE growth of few-layer 2H-MoTe2 on 3D substrates. Journal of Crystal Growth 482, 61–69 (2018). 39. Glavin, N. R. et al. Temporally and spatially resolved plasma spectroscopy in pulsed laser deposition of ultra-thin boron nitride films. Journal of Applied Physics 117, 165305–10 (2015). 40. Rigosi, A. F. et al. Preservation of Surface Conductivity and Dielectric Loss Tangent in Large-Scale, Encapsulated Epitaxial Graphene Measured by Noncontact Microwave Cavity Perturbations. Small. 13, 1700452 (2017). 41. Rigosi, A. F. et al. Electrical Stabilization of Surface Resistivity in Epitaxial Graphene Systems by Amorphous Boron Nitride Encapsulation. ACS Omega. 2(5), 2326–2332 (2017). 42. Lin, Y. F. et al. Ambipolar MoTe2 transistors and their applications in logic circuits. Adv. Mater. 26(20), 3263–9 (2014). 43. Huang, H. et al. Highly sensitive visible to infrared MoTe2 photodetectors enhanced by the photogating effect. Nanotechnology 27(44), 445201 (2016). 44. Chen, B. et al. Environmental changes in MoTe2 excitonic dynamics by defects-activated molecular interaction. ACS Nano. 9(5), 5326–5332 (2015). 45. Huang, Y. et al. Reliable exfoliation of large-area high-quality flakes of graphene and other two-dimensional materials. ACS nano. 9(11), 10612–10620 (2015). Acknowledgements The authors would like to acknowledge Dr. Juanchao Li from Materials Research Facility at University of North Texas and Dr. Adam Neal from Materials and Manufacturing Directorate, U.S. Air Force Research Laboratory (AFRL/RX) for their helpful discussions and assistance with electron beam lithography. A.V. and B.S. acknowledge support from AFRL/RX under the Education Partnership Agreement 17-020-RX-01. S. K. acknowledges support from the U.S. Department of Commerce, National Institute of Standards and Technology under the financial assistance award 70NANB16H043. Author Contributions A.A.V. managed the project and overlooked all experiments. B.S. performed MoTe material exfoliation, device fabrication via EBL, and all material characterization and electrical testing. N.G. performed the a-BN coating using PLD. S.K. and A.V.D. synthesized the bulk 2H-MoTe materials via iodine-assisted CVT technique. All authors took part in the discussion and writing of this manuscript. Additional Information Supplementary information accompanies this paper at https://doi.org/10.1038/s41598-018-26751-4. Competing Interests: The authors declare no competing interests. Publisher's note: Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Cre- ative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not per- mitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. © The Author(s) 2018 ScIEntIFIc REPO R TS | (2018) 8:8668 | DOI:10.1038/s41598-018-26751-4 8
Scientific Reports – Springer Journals
Published: Jun 6, 2018
It’s your single place to instantly
discover and read the research
that matters to you.
Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.
All for just $49/month
Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly
Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.
Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.
Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.
All the latest content is available, no embargo periods.
“Hi guys, I cannot tell you how much I love this resource. Incredible. I really believe you've hit the nail on the head with this site in regards to solving the research-purchase issue.”Daniel C.
“Whoa! It’s like Spotify but for academic articles.”@Phil_Robichaud
“I must say, @deepdyve is a fabulous solution to the independent researcher's problem of #access to #information.”@deepthiw
“My last article couldn't be possible without the platform @deepdyve that makes journal papers cheaper.”@JoseServera