A new procedure was suggested for preparing polymeric organosilanes and silanosiloxanes without using a dispersion of an alkali metal in an organic solvent. The procedure allows preparation of linear organopolysilanes —(R2Si) n —, whereas reactions of methyl-, phenyl-, and n-hexyltrichlorosilanes with Na/NaCl yield silanosiloxane derivatives [(RSi) x (RSiO y ].
Russian Journal of Applied Chemistry – Springer Journals
Published: Mar 5, 2010
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