Heterometallic nickel(II) samarium(III) diethylenetriaminepentaacetate, a starting material for the preparation of samarium nickelate films

Heterometallic nickel(II) samarium(III) diethylenetriaminepentaacetate, a starting material for... A reaction of samarium oxide, nickel oxocarbonate, and diethylenetriaminepentaacetic acid (H5DTPA) taken in stoichiometric proportions in water gave SmNiDTPA · 10H2O as a glassy solid. The formation of this heterometallic complex was confirmed by data from elemental analysis, IR spectroscopy, thermal analysis, and X-ray fluorescence analysis. An aqueous solution of the complex was used to deposit SmNiO3 films onto a single-crystal SrTiO3(001) substrate. The SmNiO3 phase in films obtained upon 3-h annealing at 500°C was identified by powder X-ray diffraction. Films deposited from a solution of an equimolar mixture of monometallic samarium and nickel diethylenetriaminepentaacetates contained no samarium nickelate. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Heterometallic nickel(II) samarium(III) diethylenetriaminepentaacetate, a starting material for the preparation of samarium nickelate films

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Publisher
Springer Journals
Copyright
Copyright © 2006 by Pleiades Publishing, Inc.
Subject
Chemistry; Inorganic Chemistry; Physical Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328406100034
Publisher site
See Article on Publisher Site

Abstract

A reaction of samarium oxide, nickel oxocarbonate, and diethylenetriaminepentaacetic acid (H5DTPA) taken in stoichiometric proportions in water gave SmNiDTPA · 10H2O as a glassy solid. The formation of this heterometallic complex was confirmed by data from elemental analysis, IR spectroscopy, thermal analysis, and X-ray fluorescence analysis. An aqueous solution of the complex was used to deposit SmNiO3 films onto a single-crystal SrTiO3(001) substrate. The SmNiO3 phase in films obtained upon 3-h annealing at 500°C was identified by powder X-ray diffraction. Films deposited from a solution of an equimolar mixture of monometallic samarium and nickel diethylenetriaminepentaacetates contained no samarium nickelate.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Oct 7, 2006

References

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