Growth and physicochemical studies on 2-amino 5-bromopyridinium 4-carboxybutanoate: an organic NLO single crystal

Growth and physicochemical studies on 2-amino 5-bromopyridinium 4-carboxybutanoate: an organic... The title compound 2-amino 5-bromopyridinium 4-carboxybutanoate (2A5BPC), has been synthesized and optical quality single crystals of 2A5BPC were grown by solution growth technique. This crystal belongs to orthorhombic system with a noncentrosymmetric space group of P212121. Its structure and compositions were confirmed by X-ray diffraction(single and powder) and microanalysis studies. The thermal stability and decomposition behaviour of 2A5BPC were investigated by simultaneous TG/DTA and DSC analysis. The temperature dependence of heat capacity of 2A5BPC was calculated by modulated DSC analysis. The thermal diffusivity, thermal conductivity, and specific heat capacity of the grown crystals, which are the three most important thermo-physical parameters in heat transfer calculations, were calculated by an improved photopyroelectric technique. The frequency conversion efficiency, dielectric behaviour, mechanical strength and optical strength of 2A5BPC were investigated through Kurtz and Perry technique, dielectric studies, Vickers microhardness tests and laser damage profile, respectively. Spectroscopic studies revealed the vibrational modes, optical transmittance in UV–Visible region, and luminscence behaviour of 2A5BPC. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Materials Science: Materials in Electronics Springer Journals

Growth and physicochemical studies on 2-amino 5-bromopyridinium 4-carboxybutanoate: an organic NLO single crystal

Loading next page...
 
/lp/springer_journal/growth-and-physicochemical-studies-on-2-amino-5-bromopyridinium-4-GrDVLwyHMt
Publisher
Springer US
Copyright
Copyright © 2017 by Springer Science+Business Media New York
Subject
Materials Science; Optical and Electronic Materials; Characterization and Evaluation of Materials
ISSN
0957-4522
eISSN
1573-482X
D.O.I.
10.1007/s10854-017-7122-0
Publisher site
See Article on Publisher Site

Abstract

The title compound 2-amino 5-bromopyridinium 4-carboxybutanoate (2A5BPC), has been synthesized and optical quality single crystals of 2A5BPC were grown by solution growth technique. This crystal belongs to orthorhombic system with a noncentrosymmetric space group of P212121. Its structure and compositions were confirmed by X-ray diffraction(single and powder) and microanalysis studies. The thermal stability and decomposition behaviour of 2A5BPC were investigated by simultaneous TG/DTA and DSC analysis. The temperature dependence of heat capacity of 2A5BPC was calculated by modulated DSC analysis. The thermal diffusivity, thermal conductivity, and specific heat capacity of the grown crystals, which are the three most important thermo-physical parameters in heat transfer calculations, were calculated by an improved photopyroelectric technique. The frequency conversion efficiency, dielectric behaviour, mechanical strength and optical strength of 2A5BPC were investigated through Kurtz and Perry technique, dielectric studies, Vickers microhardness tests and laser damage profile, respectively. Spectroscopic studies revealed the vibrational modes, optical transmittance in UV–Visible region, and luminscence behaviour of 2A5BPC.

Journal

Journal of Materials Science: Materials in ElectronicsSpringer Journals

Published: Jun 1, 2017

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Search

Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly

Organize

Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.

Access

Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve

Freelancer

DeepDyve

Pro

Price

FREE

$49/month
$360/year

Save searches from
Google Scholar,
PubMed

Create lists to
organize your research

Export lists, citations

Read DeepDyve articles

Abstract access only

Unlimited access to over
18 million full-text articles

Print

20 pages / month

PDF Discount

20% off