Group IIB metal directed complexes with flexible benzimidazole-based connector

Group IIB metal directed complexes with flexible benzimidazole-based connector Four group IIB metal complexes, namely [ZnCl2(Mbibix)] n (I), [Cd2(Ac)4(Mbibix)2] · (H2O) (II), [HgCl2(DMF)(Mbibix)]2 (III) and [HgI2(Mbibix)]2 (IV), have been achieved via the reaction of corresponding metal salts and organic spacer Mbibix (Mbibix = 1-(3-((2-methyl-1H-benzimidazol-1-yl)methyl)benzyl)-2-methyl-1Hbenzimidazole). Crystal structure analyses reveal that complex I is one-dimensional (1D) zigzag chain, whereas II, III and IV are binuclear motifs (CIF files CCDC nos. 1006224 (I), 1006225 (II), 1006226 (III), 1006227 (IV)). These structures are further stacked into 3D supramolecular architectures via hydrogen bonding and π ⋯ π interactions. The result indicates that the metal centers imparted their influences on the structures and fluorescence behaviors. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Coordination Chemistry Springer Journals

Group IIB metal directed complexes with flexible benzimidazole-based connector

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Publisher
Springer Journals
Copyright
Copyright © 2015 by Pleiades Publishing, Ltd.
Subject
Chemistry; Physical Chemistry; Inorganic Chemistry
ISSN
1070-3284
eISSN
1608-3318
D.O.I.
10.1134/S1070328415030057
Publisher site
See Article on Publisher Site

Abstract

Four group IIB metal complexes, namely [ZnCl2(Mbibix)] n (I), [Cd2(Ac)4(Mbibix)2] · (H2O) (II), [HgCl2(DMF)(Mbibix)]2 (III) and [HgI2(Mbibix)]2 (IV), have been achieved via the reaction of corresponding metal salts and organic spacer Mbibix (Mbibix = 1-(3-((2-methyl-1H-benzimidazol-1-yl)methyl)benzyl)-2-methyl-1Hbenzimidazole). Crystal structure analyses reveal that complex I is one-dimensional (1D) zigzag chain, whereas II, III and IV are binuclear motifs (CIF files CCDC nos. 1006224 (I), 1006225 (II), 1006226 (III), 1006227 (IV)). These structures are further stacked into 3D supramolecular architectures via hydrogen bonding and π ⋯ π interactions. The result indicates that the metal centers imparted their influences on the structures and fluorescence behaviors.

Journal

Russian Journal of Coordination ChemistrySpringer Journals

Published: Mar 5, 2015

References

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