Group IIB metal directed complexes with flexible benzimidazole-based connector

Group IIB metal directed complexes with flexible benzimidazole-based connector Four group IIB metal complexes, namely [ZnCl2(Mbibix)] n (I), [Cd2(Ac)4(Mbibix)2] · (H2O) (II), [HgCl2(DMF)(Mbibix)]2 (III) and [HgI2(Mbibix)]2 (IV), have been achieved via the reaction of corresponding metal salts and organic spacer Mbibix (Mbibix = 1-(3-((2-methyl-1H-benzimidazol-1-yl)methyl)benzyl)-2-methyl-1Hbenzimidazole). Crystal structure analyses reveal that complex I is one-dimensional (1D) zigzag chain, whereas II, III and IV are binuclear motifs (CIF files CCDC nos. 1006224 (I), 1006225 (II), 1006226 (III), 1006227 (IV)). These structures are further stacked into 3D supramolecular architectures via hydrogen bonding and π ⋯ π interactions. The result indicates that the metal centers imparted their influences on the structures and fluorescence behaviors. Russian Journal of Coordination Chemistry Springer Journals

Group IIB metal directed complexes with flexible benzimidazole-based connector

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Pleiades Publishing
Copyright © 2015 by Pleiades Publishing, Ltd.
Chemistry; Physical Chemistry; Inorganic Chemistry
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