Get 20M+ Full-Text Papers For Less Than $1.50/day. Start a 14-Day Trial for You or Your Team.

Learn More →

Green method to reinforce natural rubber with tunicate cellulose nanocrystals via one-pot reaction

Green method to reinforce natural rubber with tunicate cellulose nanocrystals via one-pot reaction Tunicate cellulose nanocrystals (t-CNs) isolated from marine biomass were mixed with natural rubber (NR) via two different approaches. The first approach was the green one-pot route, NR latex was first mixed with t-CNs suspension, followed by epoxidization of the mixture. Meanwhile, a two-step method, referring to the way that NR latex was first epoxidized and then mixed with t-CNs suspension, was also carried out for comparison. The interfacial interaction, thermal performance, morphology, mechanical properties and water swelling behavior were investigated. Hydrogen bonds formed in the both nanocomposites and mechanical properties improved with increasing t-CNs content. Moreover, better dispersion and enhanced interfacial interaction were achieved for one-pot method, which was ascribed to the etching effect of hydrogen peroxide on the t-CNs surface and the possible grafting reaction during one-pot process. Therefore, compared with two-step method, 20% increase in tensile strength and 50% increase in tensile modulus were achieved for one-pot method at 10 phr t-CNs content. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Cellulose Springer Journals

Green method to reinforce natural rubber with tunicate cellulose nanocrystals via one-pot reaction

Cao, Liming; Yuan, Daosheng; Fu, Xingfeng; Chen, Yukun
Cellulose , Volume 25 (8) – Jun 2, 2018
Download PDF
13 pages

Loading next page...
 
/lp/springer_journal/green-method-to-reinforce-natural-rubber-with-tunicate-cellulose-0ywqfJSRFO
Publisher
Springer Journals
Copyright
Copyright © 2018 by Springer Science+Business Media B.V., part of Springer Nature
Subject
Chemistry; Bioorganic Chemistry; Physical Chemistry; Organic Chemistry; Polymer Sciences; Ceramics, Glass, Composites, Natural Materials; Sustainable Development
ISSN
0969-0239
eISSN
1572-882X
DOI
10.1007/s10570-018-1877-1
Publisher site
See Article on Publisher Site

Abstract

Tunicate cellulose nanocrystals (t-CNs) isolated from marine biomass were mixed with natural rubber (NR) via two different approaches. The first approach was the green one-pot route, NR latex was first mixed with t-CNs suspension, followed by epoxidization of the mixture. Meanwhile, a two-step method, referring to the way that NR latex was first epoxidized and then mixed with t-CNs suspension, was also carried out for comparison. The interfacial interaction, thermal performance, morphology, mechanical properties and water swelling behavior were investigated. Hydrogen bonds formed in the both nanocomposites and mechanical properties improved with increasing t-CNs content. Moreover, better dispersion and enhanced interfacial interaction were achieved for one-pot method, which was ascribed to the etching effect of hydrogen peroxide on the t-CNs surface and the possible grafting reaction during one-pot process. Therefore, compared with two-step method, 20% increase in tensile strength and 50% increase in tensile modulus were achieved for one-pot method at 10 phr t-CNs content.

Journal

Cellulose – Springer Journals

Published: Jun 2, 2018

References

  • Poly(lactic acid)/natural rubber/cellulose nanocrystal bionanocomposites part I: Processing and morphology
    Bitinis, N; Verdejo, R; Bras, J
  • A theoretical and experimental study of filler effect on stress-deformation-segmental orientation relations for poly(-dimethylsiloxane) networks
    Bokobza, L; Erman, B
  • One-pot polymerization, surface grafting, and processing of waterborne polyurethane-cellulose nanocrystal nanocomposites
    Cao, XD; Habibi, Y; Lucia, LA
  • Preparation and properties of carboxylated styrene-butadiene rubber/cellulose anocrystals composites
    Cao, XD; Xu, CH; Liu, YH
  • High-performance natural rubber nanocomposites with marine biomass (tunicate cellulose)
    Cao, LM; Fu, XF; Xu, CH
  • Biobased, self-healable, high strength rubber with tunicate cellulose nanocrystals
    Cao, LM; Yuan, DS; Xu, CH
  • Cellulose nanocrystals reinforced foamed nitrile rubber nanocomposites
    Chen, YK; Zhang, YB; Xu, CH
  • New approach to fabricate novel fluorosilicone thermoplastic vulcanizate with bicrosslinked silicone rubber-core/fluororubbershell particles dispersed in poly(vinylidene fluoride): structure and property
    Chen, YK; Wang, YH; Xu, CH
  • Fabrication of high performance magnetic rubber from NBR and Fe3O4 via in situ compatibilization with zinc dimethacrylate
    Chen, YK; Huang, XH; Gong, Z
  • Bio-based PLA/NR-PMMA/NR ternary thermoplastic vulcanizates with balanced stiffness and toughness: “Soft–Hard” core–shell continuous rubber phase, in situ compatibilization, and properties
    Chen, YK; Wang, WT; Yuan, DS
  • Polymer nanocomposites reinforced by cellulose whiskers
    Favier, V; Chanzy, H; Cavaille, JY
  • Processing of PLA nanocomposites with cellulose nanocrystals extracted from Posidonia oceanica waste: innovative reuse of coastal plant
    Fortunati, E; Luzi, F; Puglia, D
  • High-Strength, healable, supramolecular polymer nanocomposites
    Fox, J; Wie, JJ; Greenland, BW
  • Anisotropic shape memory behaviors of polylactic acid/citric acid-bentonite composite with a gradient filler concentration in thickness direction
    Fu, LH; Wu, FD; Xu, CH
  • Segregated network formation of multiwalled carbon nanotubes in natural rubber through surfactant assisted latex compounding: a novel technique for multifunctional properties
    George, N; Bipinbal, PK; Bhadran, B
  • Poly(methyl vinyl ether-co-maleic acid)–polyethylene glycol nanocomposites cross-linked in situ with cellulose nanowhiskers
    Goetz, L; Foston, M; Mathew, AP
  • Enhanced interfacial interaction of rubber/clay nanocomposites by a novel two-step method
    Ha, QX; Wu, YP; Wang, YQ
  • Biocomposites from natural rubber: synergistic effects of functionalized cellulose nanocrystals as both reinforcing and crosslinking agents via free-radical thiol-ene chemistry
    Kanoth, BP; Claudino, M; Johansson, M
  • Physical and/or chemical compatibilization of extruded cellulose nanocrystal reinforced polystyrene nanocomposites
    Lin, N; Dufresne, A
  • Preparation, properties and applications of polysaccharide nanocrystals in advance functional nanomaterials: a review
    Lin, N; Huang, J; Dufresne, A
  • The improvement of mechanical performance and water-response of carboxylated SBR by chitin nanocrystals
    Liu, MX; Peng, Q; Luo, BH; Zhou, CR
  • Preparation of rubber/grapheme oxide composites with in situ interfacial design
    Liu, X; Kuang, WY; Guo, BC
  • Self-healing strain sensors based on nanostructured supramolecular conductive elastomers
    Liu, XH; Lu, CH; Wu, XD
  • Cellulose nanocrystal reinforced oxidized natural rubber nanocomposites
    Mariano, M; Kissi, NE; Dufresne, A
  • In-situ polymerized cellulose nanocrystals (CNC)-poly(l-lactide) (PLLA) nanomaterials and applications in nanocomposite processing
    Miao, CW; Haman, W
  • Cellulose nanomaterials review: structure, properties and nanocomposites
    Moon, RJ; Martini, A; Nairn, J
  • Review of the recent development in cellulose nanocomposites processing
    Oksman, K; Aitomaki, Y; Mathew, A
  • Strong nanocomposite reinforcement effects in polyurethane elastomer with low volume fraction of cellulose nanocrystals
    Pei, A; Malho, JM; Ruokolainen, J
  • Comparison of the properties of cellulose nanocrystals and cellulose nanofibrils isolated from bacteria, tunicate, and wood processed using acid, enzymatic, mechanical, and oxidative methods
    Sacui, IA; Nieruwendaal, RC; Burnett, DJ
  • The role of cellulose nanocrystals in the improvement of the shape-memory properties of castor oil-based segmented thermoplastic polyurethanes
    Saralegi, A; Gonzalez, ML; Valea, A
  • Elucidation of filler-to-filler and filler-to-rubber interactions in silica-reinforced natural rubber by TEM network visualization
    Sarkawi, SS; Dierkes, WK; Noordermeer, JWM
  • Polysaccharide nanocrystals as fillers for PLA based nanocomposites
    Scafaro, R; Botta, L; Lopresti, F
  • Cross-linked polyvinyl alcohol (PVA) foams reinforced with cellulose nanocrystals (CNCs)
    Song, T; Tanpichai, S; Oksman, K
  • Polylactide/cellulose nanocrystal nanocomposites: efficient routes for nanofiber modification and effects of nanofiber chemistry on PLA reinforcement
    Spinella, S; Re, GL; Liu, B
  • Preparation of butadiene–styrene–vinyl pyridine rubber–graphene oxide hybrids through co-coagulation process and in situ interface tailoring
    Tang, ZH; Wu, XH; Guo, BC
  • Bioderived rubber-cellulose nanocrystal composites with tunable water-responsive adaptive mechanical behavior
    Tian, M; Zhen, XC; Wang, ZF
  • Filler-elastomer interactions. Part VII. Study on bound rubber
    Wolff, S; Wang, MJ; Tan, EH
  • Interfacial interaction between the epoxidized natural rubber and silica in natural rubber/silica composites
    Xu, TW; Jia, ZX; Luo, YF
  • Design of self-healing supramolecular rubbers by introducing ionic cross-links into natural rubber via a controlled vulcanization
    Xu, CH; Cao, LM; Lin, BF
  • Self-healing natural rubber with tailorable mechanical properties based on ionic supramolecular hybrid network
    Xu, CH; Cao, LM; Huang, XH
  • Self-healing chitosan/vanillin hydrogels based on Schiff-base bond/hydrogen bond hybrid linkages
    Xu, CH; Zhan, W; Tang, XZ
  • Synthesis of bacterial cellulose and bacterial cellulose nanocrystals for their applications in the stabilization of olive oil pickering emulsion
    Yan, HQ; Chen, XQ; Song, HW
  • Biocompatible reduced graphene oxide sheets with superior water dispersibility stabilized by cellulose nanocrystals and their polyethylene oxide composites
    Ye, YS; Zeng, HX; Wu, J
  • Processing characteristics and thermal stabilities of gel and sol of epoxidized natural rubber
    Yu, HP; Zeng, ZQ; Lu, G
  • In situ development of self-reinforced cellulose nanocrystals based thermoplastic elastomers by atom transfer radical polymerization
    Yu, J; Wang, CP; Wang, JF
  • Preparation of novel c–6 position carboxyl corn starch by a green method and its application in flame retardance of epoxy resin
    Zhang, SD; Liu, F; Peng, HQ
  • Excellent chemical and material cellulose from tunicates: diversity in cellulose production yield and chemical and morphological structures from different tunicate species
    Zhao, YD; Li, JB
  • Tunicate cellulose nanocrystals: preparation, neat films and nanocomposite films with glucomannans
    Zhao, YD; Zhang, YJ; Lindstrom, ME