Fundamental kinetic aspects and the mechanism of oxidative dehydrogenation of 4-vinylcyclohexene into ethylbenzene and styrene on metal-containing zeolites of the pentasil family

Fundamental kinetic aspects and the mechanism of oxidative dehydrogenation of 4-vinylcyclohexene... In promotion of a Pt-Ga-containing pentasil with a binary mixture of REE oxides, a synergism of their effect on the catalyst activity in the reaction of oxidative dehydrogenation of 4-vinylcyclohexene is observed. A kinetic model of the process of oxidative dehydrogenation of 4-vinylcyclohexene is suggested. The model includes a stage-by-stage scheme and the corresponding reaction rate equations. It was found that the accumulation rate of 4-vinylcyclohexene dehydrogenation products is correlated with the isomerization capacity of the catalytic system. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Fundamental kinetic aspects and the mechanism of oxidative dehydrogenation of 4-vinylcyclohexene into ethylbenzene and styrene on metal-containing zeolites of the pentasil family

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Publisher
Springer Journals
Copyright
Copyright © 2013 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427213070057
Publisher site
See Article on Publisher Site

Abstract

In promotion of a Pt-Ga-containing pentasil with a binary mixture of REE oxides, a synergism of their effect on the catalyst activity in the reaction of oxidative dehydrogenation of 4-vinylcyclohexene is observed. A kinetic model of the process of oxidative dehydrogenation of 4-vinylcyclohexene is suggested. The model includes a stage-by-stage scheme and the corresponding reaction rate equations. It was found that the accumulation rate of 4-vinylcyclohexene dehydrogenation products is correlated with the isomerization capacity of the catalytic system.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Aug 28, 2013

References

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