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Functionalized graphene–polyaniline nanocomposite as electrode material for asymmetric supercapacitors

Functionalized graphene–polyaniline nanocomposite as electrode material for asymmetric... A polyaniline/sulfonated graphene (PANI/SG) nanostructure was synthesized as electrode material for an asymmetric supercapacitor via a novel in situ chemical oxidative polymerization method including two oxidants. The composite’s structure and morphology were characterized by Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), field-emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM) measurements. Furthermore, the electrochemical performances of the composite were characterized by cyclic voltammetry (CV), galvanostatic charge–discharge (GCD), and electrochemical impedance spectroscopy (EIS) techniques in detail. In addition, we have triumphantly manufactured an asymmetric supercapacitor (ASC) employing activated carbon (AC) and PANI/SG as the positive and negative electrodes, respectively. The ASC possessed an extended potential window (1.4 V), a remarkable cycling property (85.9% capacitance retention after 5000 cycles), and a satisfactory average energy and power density (23 Wh/kg and 6.1 kW/kg). http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Solid State Electrochemistry Springer Journals

Functionalized graphene–polyaniline nanocomposite as electrode material for asymmetric supercapacitors

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Publisher
Springer Journals
Copyright
Copyright © 2018 by Springer-Verlag GmbH Germany, part of Springer Nature
Subject
Chemistry; Physical Chemistry; Electrochemistry; Energy Storage; Characterization and Evaluation of Materials; Analytical Chemistry; Condensed Matter Physics
ISSN
1432-8488
eISSN
1433-0768
DOI
10.1007/s10008-018-4005-0
Publisher site
See Article on Publisher Site

Abstract

A polyaniline/sulfonated graphene (PANI/SG) nanostructure was synthesized as electrode material for an asymmetric supercapacitor via a novel in situ chemical oxidative polymerization method including two oxidants. The composite’s structure and morphology were characterized by Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), field-emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM) measurements. Furthermore, the electrochemical performances of the composite were characterized by cyclic voltammetry (CV), galvanostatic charge–discharge (GCD), and electrochemical impedance spectroscopy (EIS) techniques in detail. In addition, we have triumphantly manufactured an asymmetric supercapacitor (ASC) employing activated carbon (AC) and PANI/SG as the positive and negative electrodes, respectively. The ASC possessed an extended potential window (1.4 V), a remarkable cycling property (85.9% capacitance retention after 5000 cycles), and a satisfactory average energy and power density (23 Wh/kg and 6.1 kW/kg).

Journal

Journal of Solid State Electrochemistry – Springer Journals

Published: Jun 2, 2018

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