Formation and properties of hydrogenation catalysts based on palladium bisacetylacetonate and sodium tetrahydroborate

Formation and properties of hydrogenation catalysts based on palladium bisacetylacetonate and... Properties of the Pd(acac)2-nNaBH4 system in catalysis of the reactions of hydrogenation of alkenes, alkynes, and carbonyl and nitro groups were studied. A number of spectral methods (NMR, UV spectroscopy) and X-ray phase analysis were used to examine the main stages of formation of palladium hydrogenation catalysts produced in the interaction of Pd(acac)2 with sodium tetrahydroborate, and reasons for the bimodal nature of the dependence of the catalytic activity on the B/Pd ratio were considered. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Russian Journal of Applied Chemistry Springer Journals

Formation and properties of hydrogenation catalysts based on palladium bisacetylacetonate and sodium tetrahydroborate

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Publisher
SP MAIK Nauka/Interperiodica
Copyright
Copyright © 2009 by Pleiades Publishing, Ltd.
Subject
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
ISSN
1070-4272
eISSN
1608-3296
D.O.I.
10.1134/S1070427209110147
Publisher site
See Article on Publisher Site

Abstract

Properties of the Pd(acac)2-nNaBH4 system in catalysis of the reactions of hydrogenation of alkenes, alkynes, and carbonyl and nitro groups were studied. A number of spectral methods (NMR, UV spectroscopy) and X-ray phase analysis were used to examine the main stages of formation of palladium hydrogenation catalysts produced in the interaction of Pd(acac)2 with sodium tetrahydroborate, and reasons for the bimodal nature of the dependence of the catalytic activity on the B/Pd ratio were considered.

Journal

Russian Journal of Applied ChemistrySpringer Journals

Published: Dec 23, 2009

References

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