Fast selective oxidation of alcohols under solvent-free conditions

Fast selective oxidation of alcohols under solvent-free conditions A combination of acetic anhydride, H2SO4-nano silica, wet-SiO2 (60 %), and K2Cr2O7 as a new oxidizing system for the selective oxidation of different types of alcohols to the corresponding aldehydes and ketones at room temperature under solvent-free conditions is introduced. Mild reaction conditions, high yields of the products, short reaction time, no further oxidation to the corresponding carboxylic acid, and easy work-up make this new system a useful method for oxidizing alcohols. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Research on Chemical Intermediates Springer Journals

Fast selective oxidation of alcohols under solvent-free conditions

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Publisher
Springer Netherlands
Copyright
Copyright © 2012 by Springer Science+Business Media Dordrecht
Subject
Chemistry; Catalysis; Physical Chemistry; Inorganic Chemistry
ISSN
0922-6168
eISSN
1568-5675
D.O.I.
10.1007/s11164-012-0846-9
Publisher site
See Article on Publisher Site

Abstract

A combination of acetic anhydride, H2SO4-nano silica, wet-SiO2 (60 %), and K2Cr2O7 as a new oxidizing system for the selective oxidation of different types of alcohols to the corresponding aldehydes and ketones at room temperature under solvent-free conditions is introduced. Mild reaction conditions, high yields of the products, short reaction time, no further oxidation to the corresponding carboxylic acid, and easy work-up make this new system a useful method for oxidizing alcohols.

Journal

Research on Chemical IntermediatesSpringer Journals

Published: Oct 10, 2012

References

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