Various metal-doped MoO microspheres (with Ti, Zr, or Co dopants) were simply prepared by means of a one-step ultra- sonic spray pyrolysis, where the dopant metal species were used as a reducing agent to promote the synthesis of MoO . The differences in electronegativity and radius between Mo and the dopant metal species influenced the structure and catalytic activity for partial oxidation of n-dodecane. Keywords MoO · Dopant · Spray pyrolysis · Catalytic partial oxidation · n-Dodecane 1 Introduction * Kye Sang Yoo email@example.com Molybdenum dioxide (MoO ) has been extensively used * Jinsoo Kim for many applications, especially in heterogeneous cataly- firstname.lastname@example.org sis and in the manufacturing of electrode materials, due to Extended author information available on the last page of the article Vol:.(1234567890) 1 3 Facile Spray Pyrolysis Synthesis of Various Metal-Doped MoO Microspheres for Catalytic… 2511 its significant electrical conductivity [1 –9]. This attractive solution. The atomic ratios of dopant metal (M) to Mo used property is attributed to the presence of delocalized elec- in the precursor solutions were 0.03 and 0.06. trons in its valence band [10, 11]. MoO has also shown MoO microspheres doped with M (M = Co, Zr, or Ti) 2 2 high catalytic performance in the
Catalysis Letters – Springer Journals
Published: Jun 2, 2018
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